Role of Hot Electrons and Metal–Oxide Interfaces in Surface Chemistry and Catalytic
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1. Introduction 2. Reflection of electromagnetic waves at an interface 2.1. Reflection by a
nonlocal medium-the SCIB model 2.2. The quasistatic approximation 2.3. The quantum …

In this Perspective, we review recent advances in constructing high-fidelity potential energy
surfaces (PESs) from discrete ab initio points, using machine learning tools. Such PESs …

On the basis of different types of experiments, the authors develop implicitly the model of
surface-enhanced Raman scattering (SERS) of adsorbates on metal surfaces. The long …

Abstract Infrared Reflection-Absorption Spectroscopy (IRAS) is used to perform vibrational
spectroscopy of absorbed molecules in submonolayer quantities on well-defined, single …

All material bodies are surrounded by a fluctuating electromagnetic field because of the
thermal and quantum fluctuations of the current density inside them. Close to the surface of …

Infrared spectroscopy has become a useful tool to investigate surfaces. The theoretical and
experimental foundation of surface IR spectroscopy is described and selected examples are …

Femtochemistry addresses fundamental processes of chemical reaction dynamics such as
bond formation and breaking, which occur typically on a femtosecond time scale (1 fs) 10-15 …

Recent efforts to understand the interaction of large aromatic molecules with metal surfaces
are discussed. We focus exclusively on work involving the model molecule 3, 4, 9, 10 …

Intramolecular vibrational energy transfer is a process central to many physical and
chemical phenomena in molecules. Here, various theories describing the process are …