Controversies on the mechanism and kinetics of emulsion polymerization: An updated critical review
J Herrera-Ordonez - Advances in Colloid and Interface Science, 2023 - Elsevier
Conventional emulsion polymerization (EP) is a process via free radicals whose driving
force for its development has been its versatility to generate polymer colloids with ad hoc …
force for its development has been its versatility to generate polymer colloids with ad hoc …
Exploiting catalytic chain transfer polymerization for the synthesis of carboxylated latexes via sulfur‐free RAFT
A Shegiwal, AM Wemyss… - Journal of Polymer …, 2019 - Wiley Online Library
We present a systematic study of incorporating carboxyl groups into latex particles to
enhance colloidal stability and the physical properties of the latex. Statistical copolymers of …
enhance colloidal stability and the physical properties of the latex. Statistical copolymers of …
Methyl methacrylate-styrene copolymers prepared by utilizing the Trommsdorff effect in an inverted two-stage extruder
P Zhan, J Chen, A Zheng, H Shi, T Wu… - Materials Research …, 2020 - iopscience.iop.org
In this work, the influence of initial viscosity on the Trommsdorff effect was firstly investigated,
and it was confirmed that 1000±100 Pa· s of viscosity could be a criterion of the Trommsdorff …
and it was confirmed that 1000±100 Pa· s of viscosity could be a criterion of the Trommsdorff …
Patterned PHEMA Films Synthesized by Redox Polymerization for Multicellular Spheroid Generation
Y Yun, Y Guan, Y Zhang - Industrial & Engineering Chemistry …, 2019 - ACS Publications
Patterned hydrogel films are attractive for the generation of 3D multicellular spheroids, a
new in vitro cell model. Traditional methods for their synthesis, such as photolithography and …
new in vitro cell model. Traditional methods for their synthesis, such as photolithography and …
Switching from Single to Simultaneous Free‐Radical and Anionic Polymerization with Enamine‐Based Organic Electron Donors
Y Zhao, M Rollet, L Charles, G Canard… - Angewandte …, 2021 - Wiley Online Library
Although most monomers can polymerize through different propagation pathways,
polymerization‐initiating systems that can switch from one mode to another are rare. In this …
polymerization‐initiating systems that can switch from one mode to another are rare. In this …
On the diffusive step of free-radical entry in emulsion polymerization and the applicability of the Smoluchowski rate coefficient
J Herrera-Ordonez, CLA Ricardo… - Colloids and Surfaces A …, 2018 - Elsevier
An algebraic equation for estimating the rate coefficient of the diffusive step of free-radical
entry kc, is proposed. It is an extension to emulsion polymerization of the approach …
entry kc, is proposed. It is an extension to emulsion polymerization of the approach …
Operando spectroscopy for resin curing
LE Eijsink - 2022 - research.rug.nl
Coatings and paint are important in our daily lives, both for aesthetic as well as protective
purposes. In this thesis, the hardening of a particular coating material based on a mixture of …
purposes. In this thesis, the hardening of a particular coating material based on a mixture of …
Contributing to a better comprehension of: the styrene bulk free-radical polymerization with n-pentane added as a blowing agent for producing expandable …
D Victoria-Valenzuela, AB Morales-Cepeda - Journal of Polymer Research, 2022 - Springer
The kinetic study of free radical polymerization of styrene in the presence of n-pentane is a
challenging and relevant topic because of its commercial and scientific value. Although this …
challenging and relevant topic because of its commercial and scientific value. Although this …
Self-Stable Precipitation Polymerization Molecular Entanglement Effect and Molecular Weight Simulations and Experiments
J Qu, Y Gao, W Yang - Polymers, 2021 - mdpi.com
In this paper, we developed a reactive molecular dynamics (RMD) scheme to simulate the
Self-Stable Precipitation (SP) polymerization of 1-pentene and cyclopentene (C5) with …
Self-Stable Precipitation (SP) polymerization of 1-pentene and cyclopentene (C5) with …