The catalyst-directed divergent synthesis, commonly termed as “divergent catalysis”, has
emerged as a promising technique as it allows chartering of structurally distinct products …

Gold complexes have emerged as the catalysts of choice for various functionalization
reactions of C–C multiple bonds due to their inherent carbophilic nature. In a parallel space …

Presented herein is the first report of enantioselective Au (I)/Au (III) redox catalysis, enabled
by a newly designed hemilabile chiral (P, N)-ligand (ChetPhos). The potential of this concept …

Herein, we report a gold-catalyzed Heck reaction facilitated by the ligand-enabled Au (I)/Au
(III) redox catalysis. The elementary organometallic steps such as migratory insertion and β …

Abstract The first C− SCF3/SeCF3 cross‐coupling reactions using gold redox catalysis
[(MeDalphos) AuCl], AgSCF3 or Me4NSeCF3, and organohalides as substrates are …

In the last decade, major advances have been made in homogeneous gold catalysis.
However, AuI/AuIII catalytic cycle remains much less explored due to the reluctance of AuI to …

Ligand-enabled oxidative addition of Csp2-X bonds to Au (I) centers has recently appeared
as a valuable strategy for the development of catalytic RedOx processes. Several cross …

We describe a AuI complex of a hemi‐labile (C^ N) N‐heterocyclic carbene ligand that is
able to mediate oxidative addition of aryl iodides. Detailed computational and experimental …

The gold‐catalyzed intermolecular oxyarylation of alkenes is reported. This work employed
the oxidative addition of aryl iodides to Me− DalphosAu+ for the formation of a AuIII− Ar …

Reported herein is a ligand-enabled gold-catalyzed C (sp2)–O cross-coupling reaction of
aryl iodides and aliphatic alcohols. The synthesis of a variety of aryl alkyl ethers including …