Creation from Confusion and Fusion in the Porphyrin World─ The Last Three Decades of N-Confused Porphyrinoid Chemistry

M Toganoh, H Furuta - Chemical Reviews, 2022 - ACS Publications
Confusion is a novel concept of isomerism in porphyrin chemistry, delivering a steady
stream of new chemistry since the discovery of N-confused porphyrin, a porphyrin mutant, in …

Subphthalocyanines, subporphyrazines, and subporphyrins: Singular nonplanar aromatic systems

CG Claessens, D Gonzalez-Rodriguez… - Chemical …, 2014 - ACS Publications
1. INTRODUCTION Porphyrins (Ps) 1, 2 and their best known synthetic analogues, the
phthalocyanines (Pcs; 2− 10 Chart 1) represent one of the most widely studied macrocyclic …

Heterocyclic nanographenes and other polycyclic heteroaromatic compounds: synthetic routes, properties, and applications

M Stepien, E Gonka, M Żyła, N Sprutta - Chemical reviews, 2017 - ACS Publications
Two-dimensionally extended, polycyclic heteroaromatic molecules (heterocyclic
nanographenes) are a highly versatile class of organic materials, applicable as functional …

Flexible porphyrinoids

B Szyszko, MJ Białek, E Pacholska-Dudziak… - Chemical …, 2017 - ACS Publications
This review underscores the conformational flexibility of porphyrinoids, a unique class of
functional molecules, starting from the smallest triphyrins (1.1. 1) via [18] porphyrins (1.1 …

Figure eights, Möbius bands, and more: conformation and aromaticity of porphyrinoids

M Stępień, N Sprutta… - Angewandte Chemie …, 2011 - Wiley Online Library
The aromatic character of porphyrins, which has significant chemical and biological
consequences, can be substantially altered by judicious modifications of the parent ring …

Expanded, contracted, and isomeric porphyrins: Theoretical aspects

J Mack - Chemical Reviews, 2017 - ACS Publications
The use of cyclic polyene perimeter-model approaches, such as Gouterman's four-orbital
model and Michl's perimeter model, to analyze trends in the electronic structures and optical …

Blooming of confused porphyrinoids—fusion, expansion, contraction, and more confusion

M Toganoh, H Furuta - Chemical Communications, 2012 - pubs.rsc.org
This article introduces an overview of progressively developing chemistry of N-confused
porphyrin and related macrocycles. Study on confusion results in discovery of fusion and …

Confusion approach to porphyrinoid chemistry

A Srinivasan, H Furuta - Accounts of chemical research, 2005 - ACS Publications
N-confused porphyrin (NCP) is a porphyrin isomer that is different largely from the parent
porphyrin, particularly in the physical, chemical, structural, and coordination properties …

Core chemistry and skeletal rearrangements of porphyrinoids and metalloporphyrinoids

B Szyszko, L Latos-Grażyński - Chemical Society Reviews, 2015 - pubs.rsc.org
Core alteration, affording heteroporphyrinoids and carbaporphyrinoids, allows for the
exploration of porphyrin-like or porphyrin-unlike coordination chemistry. Such a strategy has …

Photophysical properties of a series of free-base corroles

T Ding, EA Alemán, DA Modarelli… - The Journal of Physical …, 2005 - ACS Publications
Four free-base corroles with electron-donating or electron-withdrawing groups on the para
or 2 through 6-positons of the meso phenyl rings were prepared via either Paolesse or …