Organic synthesis with the most abundant transition metal–iron: from rust to multitasking catalysts

S Rana, JP Biswas, S Paul, A Paik… - Chemical Society Reviews, 2021 - pubs.rsc.org
In industries and academic laboratories, several late transition metal-catalyzed prerequisite
reactions are widely performed during single and multistep synthesis. However, besides the …

3d-Metal catalyzed N-and C-alkylation reactions via borrowing hydrogen or hydrogen autotransfer

T Irrgang, R Kempe - Chemical reviews, 2018 - ACS Publications
The conservation of our element resources is a fundamental challenge of mankind. The
development of alcohol refunctionalization reactions is a possible fossil carbon conservation …

Advances in one-pot synthesis through borrowing hydrogen catalysis

A Corma, J Navas, MJ Sabater - Chemical reviews, 2018 - ACS Publications
The borrowing hydrogen (BH) principle, also called hydrogen auto-transfer, is a powerful
approach which combines transfer hydrogenation (avoiding the direct use of molecular …

Iron catalysis in reduction and hydrometalation reactions

D Wei, C Darcel - Chemical reviews, 2018 - ACS Publications
The last two decades have seen an impressive improvement of the use of iron as a
fascinating and valuable alternative transition metal in homogeneous catalysis in terms of …

Borrowing hydrogen amination reactions: a complex analysis of trends and correlations of the various reaction parameters

E Podyacheva, OI Afanasyev, DV Vasilyev… - ACS …, 2022 - ACS Publications
Borrowing hydrogen or the hydrogen autotransfer amination is a powerful approach to
create single C–N bonds, starting from stable and readily available substrates: amines and …

Manganese complexes for (de) hydrogenation catalysis: a comparison to cobalt and iron catalysts

F Kallmeier, R Kempe - Angewandte Chemie International …, 2018 - Wiley Online Library
The sustainable use of the resources on our planet is essential. Noble metals are very rare
and are diversely used in key technologies, such as catalysis. Manganese is the third most …

Recent advances in homogeneous borrowing hydrogen catalysis using earth-abundant first row transition metals

BG Reed-Berendt, K Polidano, LC Morrill - Organic & biomolecular …, 2019 - pubs.rsc.org
The review highlights the recent advances (2013-present) in the use of earth-abundant first
row transition metals in homogeneous borrowing hydrogen catalysis. The utility of catalysts …

Efficient and selective N-alkylation of amines with alcohols catalysed by manganese pincer complexes

S Elangovan, J Neumann, JB Sortais, K Junge… - Nature …, 2016 - nature.com
Borrowing hydrogen (or hydrogen autotransfer) reactions represent straightforward and
sustainable C–N bond-forming processes. In general, precious metal-based catalysts are …

Sustainable synthesis of quinolines and pyrimidines catalyzed by manganese PNP pincer complexes

M Mastalir, M Glatz, E Pittenauer… - Journal of the …, 2016 - ACS Publications
This study represents the first example an environmentally benign, sustainable, and
practical synthesis of substituted quinolines and pyrimidines using combinations of 2 …

Recent developments of manganese complexes for catalytic hydrogenation and dehydrogenation reactions

B Maji, MK Barman - Synthesis, 2017 - thieme-connect.com
Being the third most abundant transition metal in the Earth's crust (after iron and titanium)
and less toxic, reactions catalyzed by manganese are becoming very important. A large …