Multiphase oxidation of sulfur dioxide in aerosol particles: Implications for sulfate formation in polluted environments

T Liu, AWH Chan, JPD Abbatt - Environmental Science & …, 2021 - ACS Publications
Atmospheric oxidation of sulfur dioxide (SO2) forms sulfate-containing aerosol particles that
impact air quality, climate, and human and ecosystem health. It is well-known that in-cloud …

Particulate nitrate photolysis in the atmosphere

M Gen, Z Liang, R Zhang, BRG Mabato… - Environmental Science …, 2022 - pubs.rsc.org
Multiphase and heterogeneous photochemistry is an emerging component of atmospheric
and air pollution research. It is primarily driven by reactions of photochemically produced …

Extensive field evidence for the release of HONO from the photolysis of nitrate aerosols

ST Andersen, LJ Carpenter, C Reed, JD Lee… - Science …, 2023 - science.org
Particulate nitrate (pNO 3−) has long been considered a permanent sink for NO x (NO and
NO2), removing a gaseous pollutant that is central to air quality and that influences the …

[HTML][HTML] Nitrogen oxides in the free troposphere: implications for tropospheric oxidants and the interpretation of satellite NO measurements

V Shah, DJ Jacob, R Dang, LN Lamsal… - Atmospheric …, 2023 - acp.copernicus.org
Satellite-based retrievals of tropospheric NO 2 columns are widely used to infer NO x (≡
NO+ NO 2) emissions. These retrievals rely on model information for the vertical distribution …

Targeting Atmospheric Oxidants Can Better Reduce Sulfate Aerosol in China: H2O2 Aqueous Oxidation Pathway Dominates Sulfate Formation in Haze

J Gao, G Shi, Z Zhang, Y Wei, X Tian… - Environmental …, 2022 - ACS Publications
Particulate sulfate is one of the most important components in the atmosphere. The
observation of rapid sulfate aerosol production during haze events provoked scientific …

Strong electric field force at the air/water interface drives fast sulfate production in the atmosphere

Y Liu, Q Ge, T Wang, R Zhang, K Li, K Gong, L Xie… - Chem, 2024 - cell.com
How tiny aqueous aerosol droplets significantly accelerate the atmospheric multiphase
reaction remains an open question. Here, we show both experimental and theoretical …

Sulfate Formation by Photosensitization in Mixed Incense Burning–Sodium Chloride Particles: Effects of RH, Light Intensity, and Aerosol Aging

R Tang, R Zhang, J Ma, K Song… - Environmental …, 2023 - ACS Publications
Elevated particulate sulfate concentrations have been frequently observed in coastal areas
when air masses are influenced by continental emissions, especially combustion sources …

The formation and mitigation of nitrate pollution: comparison between urban and suburban environments

S Yang, B Yuan, Y Peng, S Huang… - Atmospheric …, 2022 - acp.copernicus.org
Ambient nitrate has been of increasing concern in PM 2.5, while there are still large
uncertainties in quantifying the formation of nitrate aerosol. The formation pathways of nitrate …

Photochemical reactions of glyoxal during particulate ammonium nitrate photolysis: Brown carbon formation, enhanced glyoxal decay, and organic phase formation

R Zhang, M Gen, Z Liang, YJ Li… - Environmental Science & …, 2022 - ACS Publications
Glyoxal is an important precursor of aqueous secondary organic aerosol (aqSOA). Its
photooxidation to form organic acids and oligomers and reactions with reduced nitrogen …

[HTML][HTML] Aqueous secondary organic aerosol formation from the direct photosensitized oxidation of vanillin in the absence and presence of ammonium nitrate

BRG Mabato, Y Lyu, Y Ji, YJ Li… - Atmospheric …, 2022 - acp.copernicus.org
Vanillin (VL), a phenolic aromatic carbonyl abundant in biomass burning emissions, forms
triplet excited states (3 VL∗) under simulated sunlight leading to aqueous secondary …