Mechanochemical tools for polymer materials

Y Chen, G Mellot, D van Luijk, C Creton… - Chemical Society …, 2021 - pubs.rsc.org
Mechanochemistry provides a unique approach to investigate macroscopic deformation,
failure and healing of polymer materials. The development of mechanophores–molecular …

Covalent mechanochemistry and contemporary polymer network chemistry: a marriage in the making

EM Lloyd, JR Vakil, Y Yao, NR Sottos… - Journal of the American …, 2023 - ACS Publications
Over the past 20 years, the field of polymer mechanochemistry has amassed a toolbox of
mechanophores that translate mechanical energy into a variety of functional responses …

Validation of the CoGEF method as a predictive tool for polymer mechanochemistry

IM Klein, CC Husic, DP Kovács… - Journal of the …, 2020 - ACS Publications
The development of force-responsive molecules called mechanophores is a central
component of the field of polymer mechanochemistry. Mechanophores enable the design …

Harnessing the power of force: development of mechanophores for molecular release

BA Versaw, T Zeng, X Hu, MJ Robb - Journal of the American …, 2021 - ACS Publications
Polymers that release small molecules in response to mechanical force are promising
materials for a variety of applications ranging from sensing and catalysis to targeted drug …

Mechanochemistry of gaseous reactants

C Bolm, JG Hernández - Angewandte Chemie International …, 2019 - Wiley Online Library
In recent years, the application of mechanical energy to chemical systems has repeatedly
proven beneficial to facilitate chemical transformations in various areas in chemistry. Today …

Mechano‐responsive leapfrog micelles enable interactive apoptotic and ferroptotic cancer therapy

Y Li, Y Qin, Y Shang, Y Li, F Liu, J Luo… - Advanced Functional …, 2022 - Wiley Online Library
The combination of apoptosis and ferroptosis is highly appealing in addressing the tumor
heterogeneity‐induced therapy resistance. Reactive oxygen species (ROS)‐based cancer …

Redox-copolymers for nanofiltration-enabled electrodialysis

N Kim, J Elbert, C Kim, X Su - ACS Energy Letters, 2023 - ACS Publications
Robust, energy-efficient separation technologies for desalination and the removal of organic
contaminants are critical in addressing growing concerns about water shortage and water …

Mechanically triggered small molecule release from a masked furfuryl carbonate

X Hu, T Zeng, CC Husic, MJ Robb - Journal of the American …, 2019 - ACS Publications
Stimuli-responsive polymers that release small molecules under mechanical stress are
appealing targets for applications ranging from drug delivery to sensing. Here, we describe …

A latent mechanoacid for time-stamped mechanochromism and chemical signaling in polymeric materials

Y Lin, TB Kouznetsova, SL Craig - Journal of the American …, 2019 - ACS Publications
Mechanically coupled proton transduction offers potential for stress-responsive polymeric
materials whose properties can be switched via acid-triggered coloration …

From molecules to polymers—harnessing inter‐and intramolecular interactions to create mechanochromic materials

H Traeger, DJ Kiebala, C Weder… - Macromolecular rapid …, 2021 - Wiley Online Library
The development of mechanophores as building blocks that serve as predefined weak
linkages has enabled the creation of mechanoresponsive and mechanochromic polymer …