Recent Advances in the Chemistry and Application of SF5-Compounds
M Abd El Sater, L Popek, N Blanchard, V Bizet - Synthesis, 2024 - thieme-connect.com
This review article outlines the literature from 2022 to 2024 covering developments in SF 5
chemistry. Recent synthetic methodologies of SF 5-containing building blocks are reported …
chemistry. Recent synthetic methodologies of SF 5-containing building blocks are reported …
Expanding Radical Chloropentafluorosulfanylation of Alkynes
TM Nguyen, L Popek, D Matchavariani… - Organic …, 2024 - ACS Publications
The chloropentafluorosulfanylation of alkynes is a delicate but crucial operation for
accessing SF5-alkynes that serve as substrates in numerous transformations. Dolbier's …
accessing SF5-alkynes that serve as substrates in numerous transformations. Dolbier's …
Ambiphilic Reactivity of SF5‐Alkynes Applied to Regioselective and Stereodivergent Halogenation Reactions: An Experimental and Theoretical Case Study
D Matchavariani, L Popek… - Advanced Synthesis …, 2024 - Wiley Online Library
We explored the ambiphilic reactivity of SF5‐alkynes, and we proved they can act as both
nucleophiles and electrophiles. We selected halogenation reactions as benchmark …
nucleophiles and electrophiles. We selected halogenation reactions as benchmark …
Ex-situ ChloGen: A facile and straightforward entry to Aryl-IF4 compounds
In this work, we present a new method for the facile preparation of aryl-IF 4 compounds
using KF and ex situ generated chlorine gas within a two-chamber reactor setup. Notably …
using KF and ex situ generated chlorine gas within a two-chamber reactor setup. Notably …