The oxidative dehydrogenations of amines and alcohols are promoted by their coordination
to transition metal centers, with ruthenium and osmium being particularly effective. The …

A bis (imido)-bridged dinuclear cobalt (III) complex,[Co2 (amp) 2 (μ-imp) 2Cl2] Cl2· 2H2O
(1)[amp= 2-aminomethylpyridine; imp= 2-iminomethylpyridine anion], was synthesized by …

The fragmentation of the 1, 1, 2-tris (diphenylphosphino) ethane ligand in [RuCp*((Ph2P)
2CHCH2PPh2)][PF6](1) was explored through treatment with base under aprotic conditions …

The oxidations of cis-and trans-[OsIII (tpy)(Cl) 2 (NH3)](PF6), cis-[OsII (bpy) 2
(Cl)(NH3)](PF6), and [OsII (tpy)(bpy)(NH3)](PF6) 2 have been studied by cyclic voltammetry …

Two bis (amido) ruthenium (IV) complexes,[RuIV (bpy)(LH) 2] 2+ and [RuIV (L)(LH) 2]
2+(bpy= 2, 2 '-bipyridine, L= 2, 3-diamino-2, 3-dimethylbutane, LH=(H2NCMe2CMe2NH)-) …

The mechanisms of oxidative ligand dehydrogenation in high-valent ruthenium hexaamine
complexes of bidentate 1, 2-ethanediamine (en) and tridentate 1, 1, 1-tris (aminomethyl) …

Both the fac-and mer-isomers of tricyano [bis (2-pyridylmethyl) amine= 2-DPA] ferrate (II)
were isolated and their spectroscopic properties compared. The fac-isomer was converted to …

[(n-Bu) 4N][RuNCl4] reacts with 2, 5-dimethyl-2, 5-hexanediamine (L) in acetone to give a
cationic dimeric RuVI⋮ N complex [(RuVI (L) 2N) 2 (μ-O)] Cl4 (1). The X-ray crystal structure …

Six‐coordinate osmium (III) complexes coordinated by a cyclohexanediamine‐based
tetradentate ligand [trans‐N, N′‐dimethyl‐N, N′‐bis (2‐pyridylmethyl)‐1, 2 …

Two geometrical isomers, mer-and fac-tricyano [di (2-pyridylmethyl) amine] ferrate (II) give
the iron (II) complex with dehydrogenated ligand and iron (III) complex with intact ligand …