3d transition metals for C–H activation

P Gandeepan, T Müller, D Zell, G Cera… - Chemical …, 2018 - ACS Publications
C–H activation has surfaced as an increasingly powerful tool for molecular sciences, with
notable applications to material sciences, crop protection, drug discovery, and …

Cross-dehydrogenative coupling: a sustainable reaction for C–C bond formations

T Tian, Z Li, CJ Li - Green Chemistry, 2021 - pubs.rsc.org
We are entering an era that emphasizes greenness and sustainability. Based on such a
philosophy, it is critical to uncover novel and original sustainable reaction modes for future …

Strategic evolution in transition metal-catalyzed directed C–H bond activation and future directions

S Rej, A Das, N Chatani - Coordination Chemistry Reviews, 2021 - Elsevier
In the field of C–H bond functionalization chemistry, directed C–H bond activation strategies
are highly appreciated due to the high efficiency and selectivity of such reactions towards a …

Copper-Promoted Functionalization of Organic Molecules: from Biologically Relevant Cu/O2 Model Systems to Organometallic Transformations

R Trammell, K Rajabimoghadam… - Chemical …, 2019 - ACS Publications
Copper is one of the most abundant and less toxic transition metals. Nature takes advantage
of the bioavailability and rich redox chemistry of Cu to carry out oxygenase and oxidase …

Transition‐metal‐catalyzed direct arylation of (hetero) arenes by C H bond cleavage

L Ackermann, R Vicente… - Angewandte Chemie …, 2009 - Wiley Online Library
The area of transition‐metal‐catalyzed direct arylation through cleavage of C H bonds has
undergone rapid development in recent years, and is becoming an increasingly viable …

Copper-Promoted Sulfenylation of sp2 C–H Bonds

LD Tran, I Popov, O Daugulis - Journal of the American Chemical …, 2012 - ACS Publications
An auxiliary-assisted, copper catalyzed or promoted sulfenylation of benzoic acid derivative
β-C–H bonds and benzylamine derivative γ-C–H bonds has been developed. The method …

Beyond traditional cross couplings: the scope of the cross dehydrogenative coupling reaction

CJ Scheuermann - Chemistry–An Asian Journal, 2010 - Wiley Online Library
The development of new and environmentally compatible methods for the synthesis of C C
and C heteroatom bonds is of great significance to researchers. The cross …

Recent advances in copper-mediated chelation-assisted functionalization of unactivated C–H bonds

WH Rao, BF Shi - Organic Chemistry Frontiers, 2016 - pubs.rsc.org
Transition metal-catalyzed direct functionalization of C–H bonds has recently emerged as a
powerful strategy for the construction of carbon–carbon and carbon–heteroatom bonds …

Übergangsmetallkatalysierte direkte Arylierungen von (Hetero) Arenen durch C‐H‐Bindungsbruch

L Ackermann, R Vicente, AR Kapdi - Angewandte Chemie, 2009 - Wiley Online Library
Das Gebiet der übergangsmetallkatalysierten direkten Arylierung unter C‐H‐Bindungsbruch
hat in den letzten Jahren eine rasante Entwicklung erfahren, was dazu führte, dass sich …

Cu (II)-mediated C–H amidation and amination of arenes: exceptional compatibility with heterocycles

M Shang, SZ Sun, HX Dai, JQ Yu - Journal of the American …, 2014 - ACS Publications
A Cu (OAc) 2-mediated C–H amidation and amination of arenes and heteroarenes has been
developed using a readily removable directing group. A wide range of sulfonamides …