Spin crossover nanomaterials: from fundamental concepts to devices

G Molnár, S Rat, L Salmon, W Nicolazzi… - Advanced …, 2018 - Wiley Online Library
Nanoscale spin crossover materials capable of undergoing reversible switching between
two electronic configurations with markedly different physical properties are excellent …

Sublimable spin‐crossover complexes: From spin‐state switching to molecular devices

KS Kumar, M Ruben - Angewandte Chemie International …, 2021 - Wiley Online Library
Spin‐crossover (SCO) active transition metal complexes are an important class of
switchable molecular materials due to their bistable spin‐state switching characteristics at or …

An ultrahigh energy density quasi‐solid‐state zinc ion microbattery with excellent flexibility and thermostability

J Shi, S Wang, X Chen, Z Chen, X Du… - Advanced Energy …, 2019 - Wiley Online Library
The rapid development of smart wearable and integrated electronic products has urgently
increased the requirement for high‐performance microbatteries. Although few lithium ion …

Spin‐Crossover Grafted Monolayer of a Co (II) Terpyridine Derivative Functionalized with Carboxylic Acid Groups

V García‐López, N Giaconi, L Poggini… - Advanced Functional …, 2023 - Wiley Online Library
The synthesis and characterization of a new Co (II) spin‐crossover (SCO) complex based on
4′‐(4‐carboxyphenyl)− 2, 2′: 6′, 2 ″‐terpyridine ligand are reported. This complex can …

High-voltage aqueous planar symmetric sodium ion micro-batteries with superior performance at low-temperature of− 40 ºC

X Wang, H Huang, F Zhou, P Das, P Wen, S Zheng… - Nano Energy, 2021 - Elsevier
Aqueous sodium ion micro-batteries (ANIMBs) hold great promise in smart wearable
microelectronics due to the abundant reserves, low cost and high safety of sodium …

Complete set of elastic moduli of a spin-crossover solid: Spin-state dependence and mechanical actuation

M Mikolasek, MD Manrique-Juarez… - Journal of the …, 2018 - ACS Publications
Molecular spin crossover complexes are promising candidates for mechanical actuation
purposes. The relationships between their crystal structure and mechanical properties …

Coupling mechanical and electrical properties in spin crossover polymer composites

S Rat, M Piedrahita‐Bello, L Salmon… - Advanced …, 2018 - Wiley Online Library
Spin crossover particles of formula [Fe {(Htrz) 2 (trz)} 0.9 (NH2‐trz) 0.3](BF4) 1.1 and
average size of 20 nm±8 nm are homogeneously dispersed in poly (vinylidene fluoride‐co …

Elastic Properties of the Iron(II)–Triazole Spin Crossover Complexes [Fe(Htrz)2trz]BF4 and [Fe(NH2trz)3]SO4

D Paliwoda, L Vendier, L Getzner… - Crystal Growth & …, 2023 - ACS Publications
Two benchmark Fe (II)-triazole spin-crossover (SCO) compounds,[Fe (Htrz) 2trz] BF4 (1) and
[Fe (NH2trz) 3] SO4 (2), have been investigated using variable temperature and pressure …

Control of the speed of a light-induced spin transition through mesoscale core–shell architecture

AC Felts, A Slimani, JM Cain, MJ Andrus… - Journal of the …, 2018 - ACS Publications
The rate of the light-induced spin transition in a coordination polymer network solid
dramatically increases when included as the core in mesoscale core–shell particles. A …

Micromachining‐Compatible, Facile Fabrication of Polymer Nanocomposite Spin Crossover Actuators

MD Manrique‐Juárez, F Mathieu… - Advanced Functional …, 2018 - Wiley Online Library
Abstract [FeII (Htrz) 2 (trz)](BF4) spin crossover particles of 85 nm mean size are dispersed
in an SU‐8 polymer matrix and spray‐coated onto silicon microcantilevers. The subsequent …