Machine learning approach to map the thermal conductivity of over 2,000 neoteric solvents for green energy storage applications
Interest in green neoteric solvents, such as ionic liquids (ILs) and deep eutectic solvents
(DESs), has increased dramatically in recent years due to their highly tunable properties …
(DESs), has increased dramatically in recent years due to their highly tunable properties …
[HTML][HTML] Flow chemistry as green technology for the genesis and use of organometallic reagents in the synthesis of key building blocks and APIs–An update
The advent of flow chemistry and flow microreactor technology in organic synthesis has
added a series of options to the toolbox of synthetic chemists by enabling access to …
added a series of options to the toolbox of synthetic chemists by enabling access to …
Continuous flow generation of highly reactive organometallic intermediates: a recent update
M Spennacchio, P Natho, M Andresini… - Journal of Flow …, 2024 - Springer
Reactive organometallic intermediates present a distinct opportunity for the creation of novel
carbon-carbon and carbon-heteroatom bonds. Whereas their utility in synthesis is well …
carbon-carbon and carbon-heteroatom bonds. Whereas their utility in synthesis is well …
Chiral Deep Eutectic Solvents Enable Full‐Color and White Circularly Polarized Luminescence from Achiral Luminophores
X Wen, S Du, L Zhang, M Liu - Angewandte Chemie, 2023 - Wiley Online Library
Herein, chiral deep eutectic solvents (DES) are prepared by lauric acid as hydrogen bond
donors (HBD) and chiral menthol as hydrogen bond acceptors (HBA). When achiral …
donors (HBD) and chiral menthol as hydrogen bond acceptors (HBA). When achiral …
Introducing water and deep eutectic solvents in organosodium chemistry: Chemoselective nucleophilic functionalizations in air
G Dilauro, C Luccarelli, AF Quivelli… - Angewandte Chemie …, 2023 - Wiley Online Library
Advancing the development of perfecting the use of polar organometallics in bio‐inspired
solvents, we report on the effective generation in batch of organosodium compounds, by the …
solvents, we report on the effective generation in batch of organosodium compounds, by the …
From oximes to tertiary alcohols in water, at room temperature and under air: a hybrid one-pot tandem assembly of enzymatic deoximation and RLi/RMgX reagents
D Arnodo, M Ramos-Martín, L Cicco… - Organic & …, 2023 - pubs.rsc.org
The highly efficient biodeoximation of aromatic ketoximes, promoted by the enzymatic
oxidative system laccase/TEMPO/O2, has been successfully assembled with the fast and …
oxidative system laccase/TEMPO/O2, has been successfully assembled with the fast and …
Rapid production of the anaesthetic mepivacaine through continuous, portable technology
P Díaz-Kruik, F Paradisi - Green Chemistry, 2024 - pubs.rsc.org
Local anaesthetics such as mepivacaine are key molecules in the medical sector, so
ensuring their supply chain is crucial for every health care system. Rapid production of …
ensuring their supply chain is crucial for every health care system. Rapid production of …
Recent Advancements in the Utilization of s-Block Organometallic Reagents in Organic Synthesis with Sustainable Solvents
MJ Rodríguez-Álvarez, N Ríos-Lombardía… - Molecules, 2024 - mdpi.com
This mini-review offers a comprehensive overview of the advancements made over the last
three years in utilizing highly polar s-block organometallic reagents (specifically, RLi, RNa …
three years in utilizing highly polar s-block organometallic reagents (specifically, RLi, RNa …
No life on this planet without PHB
D Seebach - Helvetica Chimica Acta, 2023 - Wiley Online Library
The history of discovery by Rosetta Reusch of oligo‐and poly‐β‐hydroxybutyrates (OHBs
and PHBs) consisting of less than ca. 150 HB units is described. These 'short …
and PHBs) consisting of less than ca. 150 HB units is described. These 'short …
A three-minute gram-scale synthesis of amines via ultrafast “on-water” in continuo organolithium addition to imines
J Brucoli, A Puglisi, S Rossi, D Gariboldi… - Cell Reports Physical …, 2024 - cell.com
Although" on-water" organic reactions, including organometallics, are a sustainable
alternative to traditional strategies, serious concerns related to the safety and feasibility of …
alternative to traditional strategies, serious concerns related to the safety and feasibility of …