Machine learning approach to map the thermal conductivity of over 2,000 neoteric solvents for green energy storage applications

T Lemaoui, AS Darwish, G Almustafa, A Boublia… - Energy Storage …, 2023 - Elsevier
Interest in green neoteric solvents, such as ionic liquids (ILs) and deep eutectic solvents
(DESs), has increased dramatically in recent years due to their highly tunable properties …

[HTML][HTML] Flow chemistry as green technology for the genesis and use of organometallic reagents in the synthesis of key building blocks and APIs–An update

P Natho, R Luisi - Tetrahedron Green Chem, 2023 - Elsevier
The advent of flow chemistry and flow microreactor technology in organic synthesis has
added a series of options to the toolbox of synthetic chemists by enabling access to …

Continuous flow generation of highly reactive organometallic intermediates: a recent update

M Spennacchio, P Natho, M Andresini… - Journal of Flow …, 2024 - Springer
Reactive organometallic intermediates present a distinct opportunity for the creation of novel
carbon-carbon and carbon-heteroatom bonds. Whereas their utility in synthesis is well …

Chiral Deep Eutectic Solvents Enable Full‐Color and White Circularly Polarized Luminescence from Achiral Luminophores

X Wen, S Du, L Zhang, M Liu - Angewandte Chemie, 2023 - Wiley Online Library
Herein, chiral deep eutectic solvents (DES) are prepared by lauric acid as hydrogen bond
donors (HBD) and chiral menthol as hydrogen bond acceptors (HBA). When achiral …

Introducing water and deep eutectic solvents in organosodium chemistry: Chemoselective nucleophilic functionalizations in air

G Dilauro, C Luccarelli, AF Quivelli… - Angewandte Chemie …, 2023 - Wiley Online Library
Advancing the development of perfecting the use of polar organometallics in bio‐inspired
solvents, we report on the effective generation in batch of organosodium compounds, by the …

From oximes to tertiary alcohols in water, at room temperature and under air: a hybrid one-pot tandem assembly of enzymatic deoximation and RLi/RMgX reagents

D Arnodo, M Ramos-Martín, L Cicco… - Organic & …, 2023 - pubs.rsc.org
The highly efficient biodeoximation of aromatic ketoximes, promoted by the enzymatic
oxidative system laccase/TEMPO/O2, has been successfully assembled with the fast and …

Rapid production of the anaesthetic mepivacaine through continuous, portable technology

P Díaz-Kruik, F Paradisi - Green Chemistry, 2024 - pubs.rsc.org
Local anaesthetics such as mepivacaine are key molecules in the medical sector, so
ensuring their supply chain is crucial for every health care system. Rapid production of …

Recent Advancements in the Utilization of s-Block Organometallic Reagents in Organic Synthesis with Sustainable Solvents

MJ Rodríguez-Álvarez, N Ríos-Lombardía… - Molecules, 2024 - mdpi.com
This mini-review offers a comprehensive overview of the advancements made over the last
three years in utilizing highly polar s-block organometallic reagents (specifically, RLi, RNa …

No life on this planet without PHB

D Seebach - Helvetica Chimica Acta, 2023 - Wiley Online Library
The history of discovery by Rosetta Reusch of oligo‐and poly‐β‐hydroxybutyrates (OHBs
and PHBs) consisting of less than ca. 150 HB units is described. These 'short …

A three-minute gram-scale synthesis of amines via ultrafast “on-water” in continuo organolithium addition to imines

J Brucoli, A Puglisi, S Rossi, D Gariboldi… - Cell Reports Physical …, 2024 - cell.com
Although" on-water" organic reactions, including organometallics, are a sustainable
alternative to traditional strategies, serious concerns related to the safety and feasibility of …