First-row d-block element-catalyzed carbon–boron bond formation and related processes

SK Bose, L Mao, L Kuehn, U Radius… - Chemical …, 2021 - ACS Publications
Organoboron reagents represent a unique class of compounds because of their utility in
modern synthetic organic chemistry, often affording unprecedented reactivity. The …

Earth-abundant transition metal catalysts for alkene hydrosilylation and hydroboration

JV Obligacion, PJ Chirik - Nature Reviews Chemistry, 2018 - nature.com
The addition of X3Si–H or X2B–H (X= H, OR or R) across a C–C multiple bond is a well-
established method for incorporating silane or borane groups, respectively, into …

Janus-type emission from a cyclometalated iron(iii) complex

J Steube, A Kruse, OS Bokareva, T Reuter… - Nature Chemistry, 2023 - nature.com
Although iron is a dream candidate to substitute noble metals in photoactive complexes,
realization of emissive and photoactive iron compounds is demanding due to the fast …

Hydride transfer reactions catalyzed by cobalt complexes

W Ai, R Zhong, X Liu, Q Liu - Chemical reviews, 2018 - ACS Publications
Cobalt has become increasingly attractive in homogeneous catalysis because of its unique
characteristics and outstanding catalytic performance in addition to being cheap and earth …

Recent advances in hydrometallation of alkenes and alkynes via the first row transition metal catalysis

J Chen, J Guo, Z Lu - Chinese Journal of Chemistry, 2018 - Wiley Online Library
Hydrometallation of alkenes and alkynes provides a straightforward route to access alkyl‐or
alkenyl‐metal reagents, which have a wide range of applications in organic transformations …

N-heterocyclic carbene complexes of copper, nickel, and cobalt

AA Danopoulos, T Simler, P Braunstein - Chemical reviews, 2019 - ACS Publications
The emergence of N-heterocyclic carbenes as ligands across the Periodic Table had an
impact on various aspects of the coordination, organometallic, and catalytic chemistry of the …

Cobalt–pincer complexes in catalysis

K Junge, V Papa, M Beller - Chemistry–A European Journal, 2019 - Wiley Online Library
Non‐noble metal catalysts based on pincer type compounds are of special interest for
organometallic chemistry and organic synthesis. Next to iron and manganese, currently …

Cobalt–N-heterocyclic carbene complexes in catalysis

SS Bera, M Szostak - ACS catalysis, 2022 - ACS Publications
Cobalt–N-heterocyclic carbene (NHC) complexes have emerged as an attractive class of 3d
transition metal catalysts for a broad range of chemical processes, including cross-coupling …

High-Oxidation-State 3d Metal (Ti–Cu) Complexes with N-Heterocyclic Carbene Ligation

J Cheng, L Wang, P Wang, L Deng - Chemical reviews, 2018 - ACS Publications
High-oxidation-state 3d metal species have found a wide range of applications in modern
synthetic chemistry and materials science. They are also implicated as key reactive species …

Recent advances in tridentate iron and cobalt complexes for alkene and alkyne hydrofunctionalizations

H Wen, G Liu, Z Huang - Coordination Chemistry Reviews, 2019 - Elsevier
The economical and sustainable nature of base metals has recently inspired extensive
investigations on the development of iron and cobalt catalysts for alkene and alkyne …