Evidence for stepwise dissociation dynamics in acetone at 248 and 193 nm
SW North, DA Blank, JD Gezelter… - The Journal of …, 1995 - pubs.aip.org
The technique of molecular beam photofragment translational spectroscopy has been used
to study the dissociation of acetone following S 1← S 0 (248 nm) and S 2← S 0 (193 nm) …
to study the dissociation of acetone following S 1← S 0 (248 nm) and S 2← S 0 (193 nm) …
Femtochemistry of Norrish Type‐I Reactions: I. Experimental and Theoretical Studies of Acetone and Related Ketones on the S1 Surface
The dissociation dynamics of two acetone isotopomers ([D0]‐and [D6] acetone) after 93 kcal
mol− 1 (307 nm) excitation to the S1 (n, π*) state have been investigated using femtosecond …
mol− 1 (307 nm) excitation to the S1 (n, π*) state have been investigated using femtosecond …
Photo induced three body decay
C Maul, KH Gericke - International Reviews in Physical Chemistry, 1997 - Taylor & Francis
The photo induced three body decay: ABC hnu ABC, where a molecule ABC decays into
three fragments A, B and C upon irradiation, is reviewed. Various experimental and …
three fragments A, B and C upon irradiation, is reviewed. Various experimental and …
Direct femtosecond observation of the transient intermediate in the α‐cleavage reaction of (CH3)2CO to 2CH3+CO: Resolving the issue of concertedness
SK Kim, S Pedersen, AH Zewail - The Journal of chemical physics, 1995 - pubs.aip.org
When a reaction involving two equivalent bonds has sufficient energy to break both of them,
it can proceed by either a concerted or a stepwise mechanism. For Norrish type‐I and other …
it can proceed by either a concerted or a stepwise mechanism. For Norrish type‐I and other …
Excited states of carbonyl compounds. 1. Formaldehyde and acetaldehyde
CM Hadad, JB Foresman… - The Journal of Physical …, 1993 - ACS Publications
Carbonyl compounds play an important role in chemistry from physical-organic to
photochemical, synthetic, and biological studies. 1 Many of these compounds have been …
photochemical, synthetic, and biological studies. 1 Many of these compounds have been …
Photodissociation dynamics
LJ Butler, DM Neumark - The Journal of Physical Chemistry, 1996 - ACS Publications
Advances in the study of photodissociation dynamics over the past 30 years are reviewed.
An overview of experimental techniques that have been developed to extract photofragment …
An overview of experimental techniques that have been developed to extract photofragment …
The ultrafast photodissociation of in the gas phase
The photodissociation dynamics of Fe (CO) 5 in a molecular beam have been investigated
with femtosecond time resolution. In single pulse experiments, the parent ion Fe (CO) 5+ …
with femtosecond time resolution. In single pulse experiments, the parent ion Fe (CO) 5+ …
UV photodissociation of oxalyl chloride yields four fragments from one photon absorption
The photodissociation of oxalyl chloride,(ClCO) 2, has been studied near 235 nm using the
photofragment imaging technique. Observed products include both ground state Cl (2 P 3/2) …
photofragment imaging technique. Observed products include both ground state Cl (2 P 3/2) …
Femtochemistry of Norrish Type‐I Reactions: III. Highly Excited Ketones—Theoretical
Time‐dependant density functional theory (TDDFT) and ab initio methods (CASSCF and
CASMP2) are applied here for the investigation of the excited‐state potential energy …
CASMP2) are applied here for the investigation of the excited‐state potential energy …
Dynamics of the acetyloxyl radical studied by dissociative photodetachment of the acetate anion
Z Lu, RE Continetti - The Journal of Physical Chemistry A, 2004 - ACS Publications
Photodetachment of the acetate anion, CH3CO2-, and the subsequent dissociation
dynamics of the CH3CO2• radical were studied using photoelectron− photofragment …
dynamics of the CH3CO2• radical were studied using photoelectron− photofragment …