Triplet pair states in singlet fission
K Miyata, FS Conrad-Burton, FL Geyer… - Chemical reviews, 2019 - ACS Publications
This account aims at providing an understanding of singlet fission, ie, the photophysical
process of a singlet state (S1) splitting into two triplet states (2× T1) in molecular …
process of a singlet state (S1) splitting into two triplet states (2× T1) in molecular …
Theoretical modeling of singlet fission
D Casanova - Chemical reviews, 2018 - ACS Publications
Singlet fission is a photophysical reaction in which a singlet excited electronic state splits
into two spin-triplet states. Singlet fission was discovered more than 50 years ago, but the …
into two spin-triplet states. Singlet fission was discovered more than 50 years ago, but the …
Singlet fission in a covalently linked cofacial alkynyltetracene dimer
Singlet fission is a process in which a singlet exciton converts into two triplet excitons. To
investigate this phenomenon, we synthesized two covalently linked 5-ethynyl-tetracene (ET) …
investigate this phenomenon, we synthesized two covalently linked 5-ethynyl-tetracene (ET) …
Charge transfer–mediated singlet fission
Singlet fission, the splitting of a singlet exciton into two triplet excitons in molecular materials,
is interesting not only as a model many-electron problem, but also as a process with …
is interesting not only as a model many-electron problem, but also as a process with …
Tuning singlet fission in π-bridge-π chromophores
E Kumarasamy, SN Sanders… - Journal of the …, 2017 - ACS Publications
We have designed a series of pentacene dimers separated by homoconjugated or
nonconjugated bridges that exhibit fast and efficient intramolecular singlet exciton fission …
nonconjugated bridges that exhibit fast and efficient intramolecular singlet exciton fission …
Dynamics of the triplet-pair state reveals the likely coexistence of coherent and incoherent singlet fission in crystalline hexacene
The absorption of a photon usually creates a singlet exciton (S1) in molecular systems, but
in some cases S1 may split into two triplets (2× T1) in a process called singlet fission. Singlet …
in some cases S1 may split into two triplets (2× T1) in a process called singlet fission. Singlet …
How morphology affects singlet fission in crystalline tetracene
GB Piland, CJ Bardeen - The journal of physical chemistry letters, 2015 - ACS Publications
The dependence of exciton dynamics on the crystalline morphology of tetracene is
investigated using time-resolved photoluminescence. Single crystals exhibit relatively slow …
investigated using time-resolved photoluminescence. Single crystals exhibit relatively slow …
Molecular insights and concepts to engineer singlet fission energy conversion devices
In this Review, we showcase the fundamental processes of intermolecular and
intramolecular singlet fission (SF). Furthermore we prioritize the information, which is …
intramolecular singlet fission (SF). Furthermore we prioritize the information, which is …
Triplet separation drives singlet fission after femtosecond correlated triplet pair production in rubrene
I Breen, R Tempelaar, LA Bizimana… - Journal of the …, 2017 - ACS Publications
Singlet fission, a multistep molecular process in which one photon generates two triplet
excitons, holds great technological promise. Here, by applying a combination of transient …
excitons, holds great technological promise. Here, by applying a combination of transient …
Maximizing singlet fission by intermolecular packing
L Wang, Y Olivier, OV Prezhdo… - The journal of physical …, 2014 - ACS Publications
A novel nonadiabatic molecular dynamics scheme is applied to study the singlet fission (SF)
process in pentacene dimers as a function of longitudinal and lateral displacements of the …
process in pentacene dimers as a function of longitudinal and lateral displacements of the …