Combined XPS and DFT investigation of the adsorption modes of methyl enol ether functionalized cyclooctyne on Si (001)

T Glaser, J Meinecke, C Länger, JN Luy… - …, 2021 - Wiley Online Library
The reaction of methyl enol ether functionalized cyclooctyne on the silicon (001) surface was
investigated by means of X‐ray photoelectron spectroscopy (XPS) and density functional …

Formation of Si/organic interfaces using alkyne-functionalized cyclooctynes—precursor-mediated adsorption of linear alkynes versus direct adsorption of cyclooctyne …

C Länger, J Heep, P Nikodemiak… - Journal of Physics …, 2018 - iopscience.iop.org
Adsorption of ethynyl-cyclopropyl-cyclooctyne (ECCO), an alkyne-functionalized
cyclooctyne, on Si (0 0 1) was studied by means of x-ray photoelectron spectroscopy (XPS) …

Dangling bonds on the Cl-and Br-terminated Si (100) surfaces

TV Pavlova, VM Shevlyuga, BV Andryushechkin… - Applied Surface …, 2022 - Elsevier
Halogen monolayer on a silicon surface is attracting active attention for applications in
electronic device fabrication with individual impurities. To create a halogen mask for the …

Complex surface chemistry of an otherwise inert solvent molecule: Tetrahydrofuran on Si (001)

G Mette, M Reutzel, R Bartholomäus, S Laref… - …, 2014 - Wiley Online Library
The reaction of tetrahydrofuran (THF), an otherwise inert solvent molecule, on Si (001) was
experimentally studied in ultra‐high vacuum. Using scanning tunneling microscopy (STM) …

Detecting and Directing Single Molecule Binding Events on H-Si (100) with Application to Ultradense Data Storage

R Achal, M Rashidi, J Croshaw, TR Huff, RA Wolkow - ACS nano, 2019 - ACS Publications
Many diverse material systems are being explored to enable smaller, more capable and
energy efficient devices. These bottom up approaches for atomic and molecular electronics …

Dissociative adsorption of diethyl ether on Si (001) studied by means of scanning tunneling microscopy and photoelectron spectroscopy

M Reutzel, G Mette, P Stromberger… - The Journal of …, 2015 - ACS Publications
The adsorption of diethyl ether (Et2O) on Si (001) was studied by means of scanning
tunneling microscopy (STM) and photoelectron spectroscopy. Et2O reacts on Si (001) via a …

Chemisorption of a strained but flexible molecule: Cyclooctyne on Si (001)

L Pecher, C Schober, R Tonner - Chemistry–A European …, 2017 - Wiley Online Library
The adsorption characteristics of a promising system for hybrid organic–inorganic interfaces,
cyclooctyne on Si (001), is analyzed using density functional theory. The chemisorbed′ on …

Site‐specific reactivity of ethylene at distorted dangling‐bond configurations on Si (001)

L Pecher, G Mette, M Dürr, R Tonner - ChemPhysChem, 2017 - Wiley Online Library
Differences in adsorption and reaction energetics for ethylene on Si (001) are reported with
respect to distorted dangling‐bond configurations induced by hydrogen precoverage, as …

Precursor states of organic adsorbates on semiconductor surfaces are chemisorbed and immobile

L Pecher, R Tonner - ChemPhysChem, 2017 - Wiley Online Library
Intermediate states to covalent attachment of molecules on surfaces, so called precursors,
are usually considered to be physisorbed and mobile. We show that this view should be …

Real-space adsorption studies of cyclooctyne on Si (0 0 1)

G Mette, M Dürr, R Bartholomäus, U Koert… - Chemical Physics …, 2013 - Elsevier
Adsorption of cyclooctyne on Si (001) was investigated by means of scanning tunneling
microscopy. Two different adsorption configurations were identified for the chemisorbed …