Photoactive copper complexes: properties and applications
J Beaudelot, S Oger, S Perusko, TA Phan… - Chemical …, 2022 - ACS Publications
Photocatalyzed and photosensitized chemical processes have seen growing interest
recently and have become among the most active areas of chemical research, notably due …
recently and have become among the most active areas of chemical research, notably due …
Improved transition metal photosensitizers to drive advances in photocatalysis
To function effectively in a photocatalytic application, a photosensitizer's light absorption,
excited-state lifetime, and redox potentials, both in the ground state and excited state, are …
excited-state lifetime, and redox potentials, both in the ground state and excited state, are …
The promise and pitfalls of photocatalysis for organic synthesis
T Noël, E Zysman-Colman - Chem Catalysis, 2022 - cell.com
Progress in photocatalysis for organic synthesis over the last 15 years has been undeniably
rapid. The number of transformations enabled by visible light has exploded as have new …
rapid. The number of transformations enabled by visible light has exploded as have new …
Heteroleptic Copper-Based Complexes for Energy-Transfer Processes: E → Z Isomerization and Tandem Photocatalytic Sequences
C Cruche, W Neiderer, SK Collins - ACS Catalysis, 2021 - ACS Publications
Energy-transfer processes involving copper complexes are rare. Using an optimized
heteroleptic copper complex, Cu (bphen)(XantPhos) BF4, photosensitized E→ Z …
heteroleptic copper complex, Cu (bphen)(XantPhos) BF4, photosensitized E→ Z …
The golden age of thermally activated delayed fluorescence materials: design and exploitation
JM Dos Santos, D Hall, B Basumatary… - Chemical …, 2024 - ACS Publications
Since the seminal report by Adachi and co-workers in 2012, there has been a veritable
explosion of interest in the design of thermally activated delayed fluorescence (TADF) …
explosion of interest in the design of thermally activated delayed fluorescence (TADF) …
Wide-bite-angle diphosphine ligands in thermally activated delayed fluorescent copper (I) complexes: impact on the performance of electroluminescence applications
We report a series of seven cationic heteroleptic copper (I) complexes of the form [Cu (P^
P)(dmphen)] BF4, where dmphen is 2, 9-dimethyl-1, 10-phenanthroline and P^ P is a …
P)(dmphen)] BF4, where dmphen is 2, 9-dimethyl-1, 10-phenanthroline and P^ P is a …
Visible Light‐Mediated Cyclisation Reaction for the Synthesis of Highly‐Substituted Tetrahydroquinolines and Quinolines
GJ Sherborne, P Kemmitt, C Prentice… - Angewandte Chemie …, 2023 - Wiley Online Library
Condensation of 2‐vinylanilines and conjugated aldehydes followed by an efficient light‐
mediated cyclisation selectively yields either substituted tetrahydroquinolines with typically …
mediated cyclisation selectively yields either substituted tetrahydroquinolines with typically …
[2+ 2] Photocycloadditions to Form Cyclobutanes and Bicyclo [2.1. 1] hexanes Employing Copper-Based Photocatalysis
G Roland, KN Hurdal, A Bouchouicha, N Dowe… - ACS …, 2024 - ACS Publications
A first-row transition metal complex, Cu (dmp)(DPEPhos) BF4, promotes the synthesis of
boracyclobutanes (11 examples, 38→ 87%) and 2-oxa-BCHs (10 examples, 55→ 90%) via …
boracyclobutanes (11 examples, 38→ 87%) and 2-oxa-BCHs (10 examples, 55→ 90%) via …
Chemoenzymatic Dynamic Kinetic Resolution of Secondary Alcohols and Amines Employing Copper-Based Photocatalysis
C Minozzi, N Dowe, N Beaucage, SK Collins - ACS Catalysis, 2023 - ACS Publications
A tandem photo-and biocatalytic dynamic kinetic resolution of secondary alcohols and
amines was achieved employing a commercially available lipase, Candida antarctica lipase …
amines was achieved employing a commercially available lipase, Candida antarctica lipase …
Unleashing the photocatalytic potential of a noble-metal-free heteroleptic copper complex-based nanomaterial for an enhanced aza-Henry reaction
In this work, we fabricated a versatile and noble metal free copper-based heterogeneous
photocatalyst, representing a green shift away from precious group metals such as Ir, Ru, Pt …
photocatalyst, representing a green shift away from precious group metals such as Ir, Ru, Pt …