Charge delocalization vs localization in carbon-rich iron mixed-valence complexes: A subtle interplay between the carbon spacer and the (dppe) Cp* Fe …

JF Halet, C Lapinte - Coordination Chemistry Reviews, 2013 - Elsevier
In this review, the electronic and structural properties of different organometallic wires
containing the (dppe) Cp* Fe organometallic electrophore are thoroughly discussed. Results …

Computational studies of the nonlinear optical properties of organometallic complexes

MS Kodikara, R Stranger, MG Humphrey - Coordination Chemistry Reviews, 2018 - Elsevier
Computational methods for calculating the molecular nonlinear optical (NLO) properties of
molecules are reviewed, with an emphasis on clarifying the strengths and weaknesses of …

Polynuclear carbon-rich organometallic complexes: clarification of the role of the bridging ligand in the redox properties

K Costuas, S Rigaut - Dalton Transactions, 2011 - pubs.rsc.org
In this Perspective, we highlight the non-innocent behaviour of the bridging ligand in
organometallic polynuclear metallic complexes displaying metal-carbon σ bonds between …

Simultaneous bridge-localized and mixed-valence character in diruthenium radical cations featuring diethynylaromatic bridging ligands

MA Fox, B Le Guennic, RL Roberts… - Journal of the …, 2011 - ACS Publications
A series of bimetallic ruthenium complexes [{Ru (dppe) Cp*} 2 (μ-C CArC C)] featuring
diethynylaromatic bridging ligands (Ar= 1, 4-phenylene, 1, 4-naphthylene, 9, 10-anthrylene) …

Bonding and substituent effects in electron-rich mononuclear ruthenium σ-Arylacetylides of the formula [(η2-dppe)(η5-C5Me5) Ru (C⋮ C)-1, 4-(C6H4) X][PF6] n (n= 0 …

F Paul, BG Ellis, MI Bruce, L Toupet, T Roisnel… - …, 2006 - ACS Publications
This study reports the isolation and the structural (X-ray), UV− vis, and NMR characterization
of a series of electron-rich Ru (II) acetylide complexes of the formula (η2-dppe)(η5-C5Me5) …

Photochromic Organometallics with a Dithienylethene (DTE) Bridge,[Y C C DTE C C Y](Y={MCp*(dppe)}): Photoswitchable Molecular Wire (M= Fe) versus …

Y Tanaka, T Ishisaka, A Inagaki, T Koike… - … A European Journal, 2010 - Wiley Online Library
Dinuclear acetylide‐type complexes bridged by a photochromic dithienylethene unit
(DTE),[Y C C DTE C C Y] 1 (Y={MCp*(dppe)}; Cp*= pentamethylcyclopentadienyl …

Di-and triferrocenyl (hetero) aromatics: Synthesis, characterization,(spectro-) electrochemistry, and calculations

U Pfaff, A Hildebrandt, D Schaarschmidt, T Hahn… - …, 2012 - ACS Publications
A series of di-and triferrocenyl (hetero) aromatics including 2, 5-diferrocenylpyridine (4), 2, 6-
diferrocenylpyridine (5), 1, 3, 5-triferrocenylbenzene (9), 2, 4, 6-triferrocenylpyridine (10) …

Di-organoiron Mixed Valent Complexes Featuring “(η2-dppe)(η5-C5Me5)Fe” Endgroups:  Smooth Class-III to Class-II Transition Induced by Successive Insertion …

SI Ghazala, F Paul, L Toupet, T Roisnel… - Journal of the …, 2006 - ACS Publications
The synthesis and study of a new redox family of symmetric dinuclear iron (II/III) complexes
featuring “(η2-dppe)(η5-C5Me5) Fe (C⋮ C)” endgroups connected by a bis (diethynyl)-4, 4 ' …

Electron transfer studies on ferrocenylthiophenes: synthesis, properties, and electrochemistry

JM Speck, R Claus, A Hildebrandt, T Rüffer… - …, 2012 - ACS Publications
The ferrocenylthiophenes 2, 3-Fc2-c C4H2S (9), 2, 4-Fc2-c C4H2S (10), and 2, 3, 4-Fc3-c
C4HS (11) have been prepared by a 2-or 3-fold Negishi cross-coupling reaction of the …

1′, 1′′′-Bis (ethynyl) biferrocene as a Linking Group for Gold, Ruthenium, and Osmium Fragments: Synthesis, Solid State Structures, and Electrochemical, UV …

M Lohan, P Ecorchard, T Rüffer, F Justaud… - …, 2009 - ACS Publications
A series of organometallic mono-and disubstituted bis (alkynyl) biferrocenes of type (LnMC
C)(HC C) bfc (LnM=(η5-C5H5)(Ph3P) 2Ru (8a),(η5-C5H5)(Ph3P) 2Os (8b),(η5 …