[HTML][HTML] Rhodium-catalyzed hydroformylation under green conditions: Aqueous/organic biphasic,“on water”, solventless and Rh nanoparticle based systems
W Alsalahi, AM Trzeciak - Coordination Chemistry Reviews, 2021 - Elsevier
Hydrofomylation is an important industrial process for aldehyde production which follows the
atom-economy principle. In this homogeneous process, the separation and subsequent …
atom-economy principle. In this homogeneous process, the separation and subsequent …
Efficient iron single-atom catalysts for selective ammoxidation of alcohols to nitriles
K Sun, H Shan, H Neumann, GP Lu, M Beller - Nature Communications, 2022 - nature.com
Zeolitic imidazolate frameworks derived Fe1-NC catalysts with isolated single iron atoms
have been synthesized and applied for selective ammoxidation reactions. For the …
have been synthesized and applied for selective ammoxidation reactions. For the …
Isosorbide: Recent advances in catalytic production
F Delbecq, MR Khodadadi, DR Padron, R Varma… - Molecular …, 2020 - Elsevier
This article focuses on the state-of-the-art advancements on the production of isosorbide, a
furanic diol exclusively produced via a two-steps dehydrocyclisation of sorbitol; polyol …
furanic diol exclusively produced via a two-steps dehydrocyclisation of sorbitol; polyol …
Cobalt-catalyzed hydroformylation under mild conditions in the presence of phosphine oxides
FG Delolo, J Yang, H Neumann… - ACS Sustainable …, 2021 - ACS Publications
In the presence of phosphine oxides, specifically triphenylphosphine oxide (P14), the cobalt-
catalyzed hydroformylation of olefins takes place under mild conditions compared to …
catalyzed hydroformylation of olefins takes place under mild conditions compared to …
Anisole: a further step to sustainable hydroformylation
FG Delolo, EN dos Santos, EV Gusevskaya - Green Chemistry, 2019 - pubs.rsc.org
Hydroformylation, also known as the “oxo” process, is a major industrial process that
employs rhodium or cobalt catalysts in solution; therefore the solvent of this process is a …
employs rhodium or cobalt catalysts in solution; therefore the solvent of this process is a …
Design of stable mixed-metal MIL-101 (Cr/Fe) materials with enhanced catalytic activity for the Prins reaction
C Vallés-García, E Gkaniatsou… - Journal of Materials …, 2020 - pubs.rsc.org
This work highlights the benefit of designing mixed-metal (Cr/Fe) MOFs for enhanced
chemical stability and catalytic activity. A robust and stable mixed-metal MIL-101 (Cr/Fe) was …
chemical stability and catalytic activity. A robust and stable mixed-metal MIL-101 (Cr/Fe) was …
Working together to avoid unwanted reactions: hydroformylation/O-acylation of terpene-based hydroxyolefins
FG Delolo, GM Vieira, JA Avendaño-Villarreal… - Journal of …, 2023 - Elsevier
The application of hydroformylation to substrates containing hydroxyl groups tends to be
problematic because the formed aldehydes can react with the hydroxyl moiety in undesired …
problematic because the formed aldehydes can react with the hydroxyl moiety in undesired …
Valorisation of biobased olefins via Rh-catalyzed transfer hydroformylation and isomerization using formaldehyde as a CO/H 2 surrogate
M Concha-Puelles, A Cortínez, N Lezana… - Catalysis Science & …, 2022 - pubs.rsc.org
The use of biomass as a new platform of chemical substrates has become a subject of
intensive research. In this sense, allylbenzenes and their isomeric analogues represent an …
intensive research. In this sense, allylbenzenes and their isomeric analogues represent an …
Sustainable route to biomass-based amines: rhodium catalyzed hydroaminomethylation in green solvents
A de Oliveira Dias, MGP Gutiérrez, JAA Villarreal… - Applied Catalysis A …, 2019 - Elsevier
The hydroaminomethylation of bio-renewable alkenes, ie, estragole, limonene, camphene
and β-pinene, was studied using di-n-butylamine, morpholine, 4-methylpiperidine or 1, 2, 3 …
and β-pinene, was studied using di-n-butylamine, morpholine, 4-methylpiperidine or 1, 2, 3 …
Upgrading biomass to high-added value chemicals: synthesis of monoterpenes-based compounds using catalytic green chemical pathways
JE Sánchez-Velandia, LA Gallego-Villada… - Catalysis …, 2024 - Taylor & Francis
Monoterpenes derived from various biomass constitute an important platform for
synthesizing fragrances, intermediates, and pharmaceuticals. In this review, the most recent …
synthesizing fragrances, intermediates, and pharmaceuticals. In this review, the most recent …