Solar-driven green synthesis of epoxides

D Tang, K Dang, J Wang, C Chen, J Zhao… - Science China …, 2023 - Springer
Epoxides are one of the most important intermediates used in the production of valuable
chemicals. Traditional preparation methods often rely on hazardous oxidants or extensive …

Palladium(II)‐Catalyzed meta‐CH Olefination: Constructing Multisubstituted Arenes through Homo‐Diolefination and Sequential Hetero‐Diolefination

M Bera, A Maji, SK Sahoo… - Angewandte Chemie …, 2015 - Wiley Online Library
Divinylbenzene derivatives represent an important class of molecular building blocks in
organic chemistry and materials science. Reported herein is the palladium‐catalyzed …

The Heck–Mizoroki cross-coupling reaction: a mechanistic perspective

JP Knowles, A Whiting - Organic & Biomolecular Chemistry, 2007 - pubs.rsc.org
The Heck–Mizoroki cross-coupling reaction is an important part of the synthetic chemist's
toolbox, and it has been applied to a huge variety of different substrates. In contrast, the …

Cyclic carbonates as green alternative solvents for the Heck reaction

HL Parker, J Sherwood, AJ Hunt… - … Sustainable Chemistry & …, 2014 - ACS Publications
Cyclic Carbonates as Green Alternative Solvents for the Heck Reaction | ACS Sustainable
Chemistry & Engineering ACS ACS Publications C&EN CAS Find my institution Log In ACS …

Mechanism, reactivity, and selectivity in palladium-catalyzed redox-relay Heck arylations of alkenyl alcohols

L Xu, MJ Hilton, X Zhang, PO Norrby… - Journal of the …, 2014 - ACS Publications
The enantioselective Pd-catalyzed redox-relay Heck arylation of acyclic alkenyl alcohols
allows access to various useful chiral building blocks from simple olefinic substrates …

Direct Pd-catalyzed arylation of 1, 2, 3-triazoles

S Chuprakov, N Chernyak, AS Dudnik… - Organic letters, 2007 - ACS Publications
Direct Pd-Catalyzed Arylation of 1,2,3-Triazoles | Organic Letters ACS ACS Publications
C&EN CAS Find my institution Log In Organic Letters ACS Publications. Most Trusted. Most …

The mechanism for the rhodium-catalyzed decarbonylation of aldehydes: a combined experimental and theoretical study

P Fristrup, M Kreis, A Palmelund… - Journal of the …, 2008 - ACS Publications
The mechanism for the rhodium-catalyzed decarbonylation of aldehydes was investigated
by experimental techniques (Hammett studies and kinetic isotope effects) and extended by a …

Mechanism and origins of ligand-controlled linear versus branched selectivity of iridium-catalyzed hydroarylation of alkenes

G Huang, P Liu - ACS Catalysis, 2016 - ACS Publications
The iridium-catalyzed carbonyl-directed hydroarylation of monosubstituted alkenes
developed by Bower and co-workers [Crisenza, GEM; McCreanor, NG; Bower, JFJ Am …

A practical in situ generation of the Schwartz reagent. Reduction of tertiary amides to aldehydes and hydrozirconation

Y Zhao, V Snieckus - Organic letters, 2014 - ACS Publications
A new, highly efficient in situ protocol (Cp2ZrCl2/LiAlH (OBu-t) 3) is described for the
generation of the Schwartz reagent which provides a convenient method for the amide to …

A computational mechanistic study of an unprecedented Heck-type relay reaction: insight into the origins of regio-and enantioselectivities

Y Dang, S Qu, ZX Wang, X Wang - Journal of the American …, 2014 - ACS Publications
Density functional theory (DFT) calculations (B3LYP and M06) have been utilized to study a
newly reported Heck-type reaction that uses an allylic or alkenyl alcohol as substrate and …