Self-assembled stereomutation with supramolecular chirality inversion

G Liu, MG Humphrey, C Zhang, Y Zhao - Chemical Society Reviews, 2023 - pubs.rsc.org
Supramolecular chirality is involved not only in biological events such as gene
communication, replication, and enzyme catalysis but also in artificial self-assembly systems …

[HTML][HTML] Artificial molecular machines

S Erbas-Cakmak, DA Leigh, CT McTernan… - Chemical …, 2015 - ACS Publications
The widespread use of molecular machines in biology has long suggested that great
rewards could come from bridging the gap between synthetic molecular systems and the …

[HTML][HTML] Stimuli-responsive synthetic helical polymers

M Lago-Silva, M Fernández-Míguez… - Chemical Society …, 2024 - pubs.rsc.org
Synthetic dynamic helical polymers (supramolecular and covalent) and foldamers share the
helix as a structural motif. Although the materials are different, these systems also share …

Inversion of Molecular Chirality Associated with Ferroelectric Switching in a High-Temperature Two-Dimensional Perovskite Ferroelectric

WF Deng, YX Li, YX Zhao, JS Hu… - Journal of the American …, 2023 - ACS Publications
Controlling molecular chirality by external stimuli is of great significance in both fundamental
research and technological applications. Herein, we report a high-temperature (384 K) …

Chirality-sensing supramolecular systems

GA Hembury, VV Borovkov, Y Inoue - Chemical reviews, 2008 - ACS Publications
Chirality that is induced, monitored, controlled, or applied via the principles of a
supramolecular approach is a modern interdisciplinary field of research that deals with …

(Nano) mechanical motion triggered by metal coordination: from functional devices to networked multicomponent catalytic machinery

A Goswami, S Saha, PK Biswas, M Schmittel - Chemical reviews, 2019 - ACS Publications
A look at the elegance and efficiency of biological machines readily reveals that Nature
masters the full gamut of chemical interactions to compose masterpieces of the living world …

Chirality sensing using stereodynamic probes with distinct electronic circular dichroism output

C Wolf, KW Bentley - Chemical Society Reviews, 2013 - pubs.rsc.org
Circular dichroism (CD) spectroscopy is one of the most useful techniques for the
stereochemical analysis of chiral biopolymers and fine chemicals. It has become invaluable …

Overtemperature-protection intelligent molecular chiroptical photoswitches

J Yao, W Wu, C Xiao, D Su, Z Zhong, T Mori… - Nature …, 2021 - nature.com
Stimuli-responsive intelligent molecular machines/devices are of current research interest
due to their potential application in minimized devices. Constructing molecular …

Acid/Base-Tunable Unimolecular Chirality Switching of a Pillar[5]azacrown Pseudo[1]Catenane

H Liang, B Hua, F Xu, LS Gan, L Shao… - Journal of the American …, 2020 - ACS Publications
Stimuli-responsive unimolecular chirality switching is a highly intriguing topic because the
molecular structure as well as its function can be adjusted simultaneously by a switching …

Solvent polarity driven helicity inversion and circularly polarized luminescence in chiral aggregation induced emission fluorophores

Q Ye, F Zheng, E Zhang, HK Bisoyi, S Zheng… - Chemical …, 2020 - pubs.rsc.org
Development of functional materials capable of exhibiting chirality tunable circularly
polarized luminescence (CPL) is currently in high demand for potential technological …