Heck reaction is one of the most important carbon‐carbon bond forming reactions with wide
applications in organic synthesis. Considerable advances of enantioselective Heck reaction …

Homogeneous catalytic reactions are typically controlled by the stereoelectronic nature of
the ligand (s) that bind to the metal (s). The advantages of the so-called first coordination …

Ligand-controlled reactivity plays an important role in transition-metal catalysis, enabling a
vast number of efficient transformations to be discovered and developed. However, a single …

The catalytic enantioselective synthesis of α‐chiral alkenes and alkynes represents a
powerful strategy for rapid generation of molecular complexity. Herein, we report a transient …

Comprehensive Summary “Chain‐walking” reactions could realize to modify a molecule at
the position far away from the active site. It has been a hot topic in the research field of …

The remote functionalization of α, β-unsaturated carbonyls by an array of multimetallic
sequential catalytic systems is described. The reactions are triggered by hydrometalation …

This Review summarizes the advances in the catalytic enantioselective mono‐and
difunctionalization of alkenes, highlighting the fundamental role of ligands. Several types of …

This study presents an improved synthetic route to ligand (S)-4-(tert-butyl)-2-(5-
(trifluoromethyl) pyridin-2-yl)-4, 5-dihydrooxazole and its application as a highly active and …

Exploration of novel, three‐dimensional chemical space is of growing interest in the drug
discovery community and with this comes the challenge for synthetic chemists to devise new …

The integration of machine learning (ML) methods into chemical catalysis is evolving as a
new paradigm for cost and time economic reaction development in recent times. Although …