Recent advances for alkylation of ketones and secondary alcohols using alcohols in homogeneous catalysis

DY Yang, H Wang, CR Chang - Advanced Synthesis & …, 2022 - Wiley Online Library
The alkylation of ketones or secondary alcohols using alcohols as alkylating agents via
hydrogen borrowing strategy presents a powerful method for the synthesis of ɑ‐alkylated …

Alcohols as Substrates in Transition-Metal-Catalyzed Arylation, Alkylation, and Related Reactions

A Cook, SG Newman - Chemical Reviews, 2024 - ACS Publications
Alcohols are abundant and attractive feedstock molecules for organic synthesis. Many
methods for their functionalization require them to first be converted into a more activated …

Nonbifunctional Outer-Sphere Strategy Achieved Highly Active α-Alkylation of Ketones with Alcohols by N-Heterocyclic Carbene Manganese (NHC-Mn)

XB Lan, Z Ye, M Huang, J Liu, Y Liu, Z Ke - Organic letters, 2019 - ACS Publications
The unusual nonbifunctional outer-sphere strategy was successfully utilized in developing
an easily accessible N-heterocyclic carbene manganese (NHC-Mn) system for highly active …

NNN Pincer Ru (II)-complex-catalyzed α-alkylation of ketones with alcohols

XN Cao, XM Wan, FL Yang, K Li, XQ Hao… - The Journal of …, 2018 - ACS Publications
A series of novel ruthenium (II) complexes supported by a symmetrical NNN ligand were
prepared and fully characterized. These complexes exhibited good performance in transfer …

Lignin-derived Zn single atom/N-codoped porous carbon for α-alkylation of aromatic ketones with alcohols via borrowing hydrogen strategy

X Zhang, GP Lu, K Wang, Y Lin, P Wang, W Yi - Nano Research, 2022 - Springer
A green and scalable strategy has been developed for the synthesis of lignin-derived Zn
single atom/N-codoped porous carbon (LCN@ Zn-SAC) containing similar ZnN x sites with …

Sustainable and selective alkylation of deactivated secondary alcohols to ketones by non‐bifunctional pincer N‐heterocyclic carbene manganese

XB Lan, Z Ye, J Liu, M Huang, Y Shao, X Cai… - …, 2020 - Wiley Online Library
A sustainable and green route to access diverse functionalized ketones via dehydrogenative–
dehydrative cross‐coupling of primary and secondary alcohols is demonstrated. This …

Manganese (I)-Catalyzed Cross-Coupling of Ketones and Secondary Alcohols with Primary Alcohols

SS Gawali, BK Pandia, S Pal, C Gunanathan - ACS omega, 2019 - ACS Publications
Catalytic cross-coupling of ketones and secondary alcohols with primary alcohols is
reported. An abundant manganese-based pincer catalyst catalyzes the reactions. Low …

Palladacycle-phosphine catalyzed methylation of amines and ketones using methanol

R Mamidala, P Biswal, MS Subramani… - The Journal of …, 2019 - ACS Publications
Methylation of amines and ketones with palladacycle precatalyst has been performed using
methanol as an environmentally benign reagent. Various ketones and amines undergo …

Iridium (I)-catalyzed alkylation reactions to form α-alkylated ketones

S Genç, S Günnaz, B Çetinkaya… - The Journal of …, 2018 - ACS Publications
A highly effective and green procedure for the formation of α-alkylated ketones has been
disclosed via the reaction of primary alcohols with secondary alcohols and ketones by using …

Ruthenium-Catalyzed β-Alkylation of Secondary Alcohols and α-Alkylation of Ketones via Borrowing Hydrogen: Dramatic Influence of the Pendant N-Heterocycle

C Zhang, JP Zhao, B Hu, J Shi, D Chen - Organometallics, 2019 - ACS Publications
Three bidentate ruthenium (II) complexes with a pyridonate fragment were prepared and
fully characterized. These complexes are structurally similar, but differ in their pendant …