Here we present the first example of a single-site main group catalyst stabilized by a metal–
organic framework (MOF) for organic transformations. The straightforward metalation of the …

This chapter provides details of the recent progress in heavier Group 2-catalyzed small
molecule transformations mediated by well-defined heteroleptic and homoleptic complexes …

The N‐alkylation of amines or ammonia with alcohols is a valuable route for the synthesis of
N‐alkyl amines. However, as a potentially clean and economic choice for N‐alkyl amine …

The heavier group 2 complexes [M {N (SiMe3) 2} 2] 2 (1, M= Ca; 2, M= Sr) and [M {CH
(SiMe3) 2} 2 (THF) 2](3, M= Ca; 4, M= Sr) are shown to be effective precatalysts for the …

This review examines the role that the bis-trimethylsilylamido group,[N {SiMe 3} 2]–, has had
on the development of the chemistry of the group 1 and group 2 (s-block) metals. Key …

The heterometallic complex [Co4Fe2OSae8]· 4DMF· H2O (1) was synthesized by one-pot
reaction of cobalt powder with iron chloride in a dimethylformamide solution of salicylidene …

The selective and asymmetric addition of amines across alkene C= C bonds
(hydroamination of alkenes) is one of the most important tool to synthesise chiral amines …

The article provides information on a study which emphasized the benefit of applying
concepts across the traditional borders of homogenous, heterogeneous and biocatalysis …

A cationic Ir (I)-C3-TUNEPHOS complex catalyzed an intermolecular hydroamination of
styrene derivatives with various heteroaromatic amines. The reaction gave Markovnikov …

Imines are valuable key compounds for synthesizing several nitrogen-containing molecules
used in biological and industrial fields. They have been obtained, as highly regioselective …