Intrinsically self-healing polymers: from mechanistic insight to current challenges
Self-healing materials open new prospects for more sustainable technologies with improved
material performance and devices' longevity. We present an overview of the recent …
material performance and devices' longevity. We present an overview of the recent …
Vitrimers: Current research trends and their emerging applications
The development of recyclable plastics is a key research focus in today's world due to their
environmental issues, and non-renewability concerns. Recently, vitrimeric materials have …
environmental issues, and non-renewability concerns. Recently, vitrimeric materials have …
Elastic vitrimers: Beyond thermoplastic and thermoset elastomers
Thermoset elastomers are widely used in industry and frontier research due to their
advantage of mechanical robustness, high thermal/chemical resistance, and good …
advantage of mechanical robustness, high thermal/chemical resistance, and good …
Vitrimers: Permanently crosslinked polymers with dynamic network topology
NJ Van Zee, R Nicolaÿ - Progress in Polymer Science, 2020 - Elsevier
The study of synthetic organic polymers rapidly expanded since Staudinger's recognition of
the covalent structure of macromolecules. Today, these materials are far from just an …
the covalent structure of macromolecules. Today, these materials are far from just an …
Adaptable crosslinks in polymeric materials: resolving the intersection of thermoplastics and thermosets
The classical division of polymeric materials into thermoplastics and thermosets based on
covalent network structure often implies that these categories are distinct and irreconcilable …
covalent network structure often implies that these categories are distinct and irreconcilable …
Vitrimers: directing chemical reactivity to control material properties
The development of more sustainable materials with a prolonged useful lifetime is a key
requirement for a transition towards a more circular economy. However, polymer materials …
requirement for a transition towards a more circular economy. However, polymer materials …
Reprocessable cross-linked polymer networks: are associative exchange mechanisms desirable?
BR Elling, WR Dichtel - ACS Central Science, 2020 - ACS Publications
Covalent adaptable networks (CANs) are covalently cross-linked polymers that may be
reshaped via cross-linking and/or strand exchange at elevated temperatures. They …
reshaped via cross-linking and/or strand exchange at elevated temperatures. They …
Dynamic covalent bonds in polymeric materials
P Chakma, D Konkolewicz - Angewandte Chemie International …, 2019 - Wiley Online Library
Dynamic covalent bonds (DCBs) have received significant attention over the past decade.
These are covalent bonds that are capable of exchanging or switching between several …
These are covalent bonds that are capable of exchanging or switching between several …
Healable and self-healing polyurethanes using dynamic chemistry
RH Aguirresarobe, S Nevejans, B Reck, L Irusta… - Progress in Polymer …, 2021 - Elsevier
Ever since the emergence of polymers, there has been interest in the production of “self-
healing” materials. Over the last decade this dream has become closer to reality with the …
healing” materials. Over the last decade this dream has become closer to reality with the …
Fast dynamic siloxane exchange mechanism for reshapable vitrimer composites
T Debsharma, V Amfilochiou… - Journal of the …, 2022 - ACS Publications
To develop siloxane-containing vitrimers with fast dynamic characteristics, different
mechanistic pathways have been investigated using a range of catalysts. In particular, one …
mechanistic pathways have been investigated using a range of catalysts. In particular, one …