Dioxygen in polyoxometalate mediated reactions

IA Weinstock, RE Schreiber, R Neumann - Chemical reviews, 2017 - ACS Publications
In this review article, we consider the use of molecular oxygen in reactions mediated by
polyoxometalates. Polyoxometalates are anionic metal oxide clusters of a variety of …

Recent advances in hybrid materials of metal nanoparticles and polyoxometalates

K Xia, K Yamaguchi, K Suzuki - … Chemie International Edition, 2023 - Wiley Online Library
Abstract Polyoxometalates (POMs), anionic metal‐oxygen nanoclusters that possess various
composition‐dependent properties, are widely used to modify the existing properties of …

Direct Oxygen Transfer from H2O to Cyclooctene over Electron‐Rich RuO2 Nanocrystals for Epoxidation and Hydrogen Evolution

X Lin, Z Zhou, QY Li, D Xu, SY Xia, BL Leng… - Angewandte …, 2022 - Wiley Online Library
Production of more than 20 million tons of epoxides per year from olefins suffers from low
atom economy due to the use of oxidants and complex catalysts with unsatisfactory …

Supported heterogeneous nanocatalysts in sustainable, selective and eco-friendly epoxidation of olefins

AS Sharma, VS Sharma, H Kaur, RS Varma - Green Chemistry, 2020 - pubs.rsc.org
Epoxides are highly useful intermediates in the production of many chemicals,
pharmaceuticals, perfumes, and polymers. In view of the continuing demand for epoxides, it …

In situ synthesis of SERS-active Au@ POM nanostructures in a microfluidic device for real-time detection of water pollutants

M Lafuente, I Pellejero, A Clemente… - … applied materials & …, 2020 - ACS Publications
We present a simple, versatile, and low-cost approach for the preparation of surface-
enhanced Raman spectroscopy (SERS)-active regions within a microfluidic channel 50 cm …

A novel amphiphilic phase transfer catalyst for the green epoxidation of soybean oil with hydrogen peroxide

F Zhang, Y Dong, S Lin, X Gui, J Hu - Molecular Catalysis, 2023 - Elsevier
Epoxidized soybean oil (ESO) is a vital organic renewable chemical material widely used in
the preparation of biomaterials. In this paper, a novel amphiphilic phase transfer catalyst [(C …

Biomass derived chemicals: Furfural oxidative esterification to methyl-2-furoate over gold catalysts

M Manzoli, F Menegazzo, M Signoretto, D Marchese - Catalysts, 2016 - mdpi.com
The use of heterogeneous catalysis to upgrade biomass wastes coming from lignocellulose
into higher value-added chemicals is one of the most explored subjects in the prospective …

Heterogeneous gold catalysis: from discovery to applications

AS Alshammari - Catalysts, 2019 - mdpi.com
In the present review, the important and current developments of gold catalysts for a wide
range of applications are comprehensively summarized. This review also provides a …

Visible light-induced aerobic epoxidation of α, β-unsaturated ketones mediated by amidines

Y Wu, G Zhou, Q Meng, X Tang, G Liu… - The Journal of …, 2018 - ACS Publications
An aerobic photoepoxidation of α, β-unsaturated ketones driven by visible light in the
presence of tetramethylguanidine (3b), tetraphenylporphine (H2TPP), and molecular oxygen …

Activation of atomically precise silver clusters on carbon supports for styrene oxidation reactions

KO Sulaiman, V Sudheeshkumar, RWJ Scott - RSC advances, 2019 - pubs.rsc.org
Metal clusters have distinct features such as large surface area, low-coordination-atom
enriched surfaces, and discrete energy levels that influence their behavior during catalytic …