A critical appraisal of RAFT-mediated polymerization-induced self-assembly

SL Canning, GN Smith, SP Armes - Macromolecules, 2016 - ACS Publications
Recently, polymerization-induced self-assembly (PISA) has become widely recognized as a
robust and efficient route to produce block copolymer nanoparticles of controlled size …

Chemical and physical chitosan hydrogels as prospective carriers for drug delivery: A review

B Tian, S Hua, Y Tian, J Liu - Journal of Materials Chemistry B, 2020 - pubs.rsc.org
With the advancement of medical research, the source and preparation of biological
materials have gradually attracted attention. Hydrogels prepared from natural …

50th Anniversary Perspective: RAFT PolymerizationA User Guide

S Perrier - Macromolecules, 2017 - ACS Publications
This Perspective summarizes the features and limitations of reversible addition–
fragmentation chain transfer (RAFT) polymerization, highlighting its strengths and …

Block copolymer vitrimers

JJ Lessard, GM Scheutz, SH Sung… - Journal of the …, 2019 - ACS Publications
In this report, we merge block copolymers with vitrimers in an effort to realize the prospect of
higher-order, nanoscale control over associative cross-link exchange and flow. We show the …

Catalyst-free vitrimers from vinyl polymers

JJ Lessard, LF Garcia, CP Easterling, MB Sims… - …, 2019 - ACS Publications
Cross-linked networks feature exceptional chemical and mechanical resilience but
consequently lack recyclability. Vitrimers have emerged as a class of materials that feature …

A guide to the synthesis of block copolymers using reversible-addition fragmentation chain transfer (RAFT) polymerization

DJ Keddie - Chemical Society Reviews, 2014 - pubs.rsc.org
The discovery of reversible-deactivation radical polymerization (RDRP) has provided an
avenue for the synthesis of a vast array of polymers with a rich variety of functionality and …

RAFT agent design and synthesis

DJ Keddie, G Moad, E Rizzardo, SH Thang - Macromolecules, 2012 - ACS Publications
This Perspective reviews the design and synthesis of RAFT agents. First, we briefly detail the
basic design features that should be considered when selecting a RAFT agent or macro …

Applications of orthogonal “click” chemistries in the synthesis of functional soft materials

RK Iha, KL Wooley, AM Nystrom, DJ Burke… - Chemical …, 2009 - ACS Publications
Applications for advanced functional soft materials that possess precisely engineered
properties and functional groups have been expanding significantly with the development of …

Cellulose modification by polymer grafting: a review

D Roy, M Semsarilar, JT Guthrie… - Chemical Society Reviews, 2009 - pubs.rsc.org
This critical review is concerned with the recent advances in graft polymerisation techniques
involving cellulose and its derivatives. It summarises some of the features of cellulose …

Controlled/living radical polymerization: Features, developments, and perspectives

WA Braunecker, K Matyjaszewski - Progress in polymer science, 2007 - Elsevier
Recent mechanistic developments in the field of controlled/living radical polymerization
(CRP) are reviewed. Particular emphasis is placed on structure–reactivity correlations and …