A photo-induced transition-metal-free regioselective hydroborylation of α, β-unsaturated
carbonyl compounds is developed. The PhSSPh reagent was employed as the …

The catalytic activity of actinide-based catalysts is presented herein for the hydroboration
and deoxygenation of isocyanates with pinacolborane (HBpin). A modified class of ligand …

Zinc dihydride complexes supported by bulky N‐heterocyclic carbenes (NHC) are efficient
catalysts in hydroboration reactions. Herein, a set of zinc complexes with an amino‐pyrrolide …

Organoboron compounds demonstrate diverse applications in the fields of organic
synthesis, materials science, and medicinal chemistry. Compared to the conventional …

We report hydroboration of carbodiimide and isocyanate substrates catalyzed by a cyclic
carbodiphosphorane catalyst. The cyclic carbodiphosphorane outperformed the other Lewis …

Reductive functionalization of CO2 for the synthesis of valuable formamide derivatives
remains a challenge. Herein, we report a heteroditopic NHC ligand-supported environment …

Alkaline-earth metals have attracted increasing attention because they are cheap, Earth
abundant and environmentally friendly, and have gradually become inexpensive and …

Three new IPr-Ag-and-Au-SNS amido and thiolate complexes were synthesized and
compared to their previously reported Cu analogues as carbonyl hydroboration catalysts …

Catalytic hydroboration and hydrosilylation have emerged as promising strategies for the
reduction of unsaturated hydrocarbons and carbonyl compounds, as well as for the …

The low-oxidation-state silicon-catalyzed hydroboration of isocyanates with pinacolborane
(HBpin) using the NHC-silyliumylidene cation catalyst [(IMe) 2SiH] I (1, IMe=: C {N (Me) C …