The synthesis of mixed-component metal-organic frameworks (MOFs)–including multivariate
MOFs (MTV-MOFs), multicomponent MOFs, mixed-metals MOFs and mixed-ligands and …

Abstract Metal-organic Frameworks (MOFs) represent a growing field of materials that are
receiving widespread attention due to their fascinating structures, intriguing properties, and …

We report a strategy to develop heterogeneous single‐site enantioselective catalysts based
on naturally occurring amino acids and earth‐abundant metals for eco‐friendly asymmetric …

Heterogeneous catalysis has great application potential in numerous industries and
significant role in global economic development. The high speed of catalyzed reactions and …

PCM-102 is a new organophosphine metal–organic framework (MOF) featuring diphosphine
pockets that consist of pairs of offset trans-oriented P (III) donors. Postsynthetic addition of M …

Upcycling nonbiodegradable plastics such as polyolefins is paramount due to their ever-
increasing demand and landfills after usage. Catalytic hydrogenolysis is highly appealing to …

Metal‐organic frameworks (MOFs) provide uniquely tunable, periodic platforms for site‐
isolation of reactive low‐valent metal complexes of relevance in modern catalysis …

Structural insight into reactive species can be achieved via strategies such as matrix
isolation in frozen glasses, whereby species are kinetically trapped, or by confinement within …

Developments in the confinement of phosphines within micro-or nano-environments are
explored. Phosphines are ubiquitous across metal coordination chemistry and underpin …

Phosphine‐functionalized metal‐organic frameworks (P‐MOFs) as an emerging class of
coordination polymers, have provided novel opportunities for the development of …