Low-valent transition metalate anions in synthesis, small molecule activation, and catalysis

VR Landaeta, TM Horsley Downie, R Wolf - Chemical Reviews, 2024 - ACS Publications
This review surveys the synthesis and reactivity of low-oxidation state metalate anions of the
d-block elements, with an emphasis on contributions reported between 2006 and 2022 …

Investigation of Iron Silyl Complexes as Active Species in the Catalytic Hydrosilylation of Aldehydes and Ketones

CV Thompson, HD Arman, ZJ Tonzetich - Organometallics, 2022 - ACS Publications
Fe (II) hydride and silyl species of the type [Fe (X)(L)(CyPNP)](X= H or SiR3; L= N2 and/or
PMe2Ph; CyPNP= anion of 2, 5-bis (dicylcohexylphosphinomethyl) pyrrole) serve as active …

Nickel (II) complexes bearing 8-hydroxyquinoline-imine ligands: Synthesis and catalysis in hydrosilylation of aldehydes and ketones

Z Hao, T Gao, X Zhou, Z Ma, Z Han, GL Lu… - Journal of Molecular …, 2023 - Elsevier
Abstract Treatment of Ni (OAc) 2⋅ 4H 2 O with 8-hydroxylquinoline-imine ligands [2-(ArN=
HC)-8-OH] C 9 H 5 N (Ar= 2, 6-i Pr 2 C 6 H 3, L1H; Ar= 2, 4, 6-(Me) 3 C 6 H 2, L2H; Ar= 4 …

Bis‐Dianionic β‐Ketoiminato Octalithium Complex Catalyzed Hydrosilylation and Cyanosilylation of Carbonyl Compounds

X Zhu, S Zhou, X Xu, Y Zheng, M Xue - ChemistrySelect, 2023 - Wiley Online Library
A well‐defined bis‐dianionic β‐ketoiminato octalithium complex was employed as an
efficient catalyst for the hydrosilylation of aldehydes and ketones. Various corresponding …

Iron and Manganese Catalyzed Hydrosilylation Reactions

T Aneeja, PXT Rinu, G Anilkumar - Perspectives of Hydrosilylation …, 2023 - Springer
Hydrosilylation reaction has emerged as an important strategy for the preparation of silicone
polymers and functionalized silanes. Most of the reports on hydrosilylation reactions rely on …