1, 1, 1, 3, 3, 3-Hexafluoroisopropanol (HFIP) is a polar, strongly hydrogen bond-donating
solvent that has found numerous uses in organic synthesis due to its ability to stabilize ionic …

Transition-metal-catalysed carbene insertion reaction is a straightforward and efficient
protocol for the construction of carbon–carbon or carbon–heteroatom bonds. Compared to …

We leveraged the recent increase in synthetic accessibility of SF5Cl and Ar− SF4Cl
compounds to combine chemistry of the SF5 and SF4Ar groups with strain‐release …

Diaryl ethers are important structural motifs widely found in bioactive natural products,
ligands, and catalysts. While there are a variety of methods available to generate diaryl …

Heterobimetallic bismuth–rhodium paddlewheel complexes with phenylglycine ligands
carrying TIPS-groups at the meta-positions of the aromatic ring exhibit outstanding levels of …

A heteroleptic dirhodium paddlewheel complex comprising three chiral carboxylate ligands
and one achiral acetamidate ligand has recently been found to be uniquely effective in …

The nickel catalyzed reductive coupling of aldehydes with sorbate esters and related
electron-deficient 1, 3-dienes are known in the literature to occur at the π-bond proximal to …

Abstract β-Chiral sulfones are structural motifs widely found in natural products and
bioactive molecules, while also serving as important intermediates for the synthesis of …

Abstract Although 2‐furyl‐carbenes (furfurylidenes) are prone to instantaneous electrocyclic
ring opening, chiral [BiRh]‐paddlewheel complexes empowered by London dispersion …

The isolation and catalytic enantioselective synthesis of configurationally stable S‐
stereogenic sulfonium ylides have been significant challenges in the field of asymmetric …