Thermo-, Electro-, and Photocatalytic CO2 Conversion to Value-Added Products over Porous Metal/Covalent Organic Frameworks

QJ Wu, J Liang, YB Huang, R Cao - Accounts of Chemical …, 2022 - ACS Publications
Conspectus The continuing increase of the concentration of atmospheric CO2 has caused
many environmental issues including climate change. Catalytic conversion of CO2 using …

Doping regulation in transition metal compounds for electrocatalysis

A Zhang, Y Liang, H Zhang, Z Geng… - Chemical Society Reviews, 2021 - pubs.rsc.org
In electrocatalysis, doping regulation has been considered as an effective method to
modulate the active sites of catalysts, providing a powerful means for creating a large variety …

Improving CO2-to-C2+ Product Electroreduction Efficiency via Atomic Lanthanide Dopant-Induced Tensile-Strained CuOx Catalysts

J Feng, L Wu, S Liu, L Xu, X Song… - Journal of the …, 2023 - ACS Publications
Cu is a promising electrocatalyst in CO2 reduction reaction (CO2RR) to high-value C2+
products. However, as important C–C coupling active sites, the Cu+ species is usually …

A stable and conductive covalent organic framework with isolated active sites for highly selective electroreduction of carbon dioxide to acetate

XF Qiu, JR Huang, C Yu, ZH Zhao, HL Zhu… - Angewandte …, 2022 - Wiley Online Library
Electroreduction of CO2 to acetate provides a promising strategy to reduce CO2 emissions
and store renewable energy, but acetate is usually a by‐product. Here, we show a stable …

Enlarging the Ni–O bond polarizability in a phosphorene-hosted metal–organic framework for boosted water oxidation electrocatalysis

W Zhai, Y Chen, Y Liu, T Sakthivel, Y Ma, Y Qin, Y Qu… - ACS …, 2023 - ACS Publications
The emerging lattice-oxygen oxidation mechanism (LOM) presents attractive opportunities
for breaking the scaling relationship to boost oxygen evolution reaction (OER) with the direct …

Dynamic Evolution of Active Sites in Electrocatalytic CO2 Reduction Reaction: Fundamental Understanding and Recent Progress

W Lai, Z Ma, J Zhang, Y Yuan, Y Qiao… - Advanced Functional …, 2022 - Wiley Online Library
Advancing the development of electrocatalytic CO2 reduction reaction (CO2RR) to address
the environmental issues caused by excessive consumption of fossil fuels requires rational …

Oxygen vacancy-rich hierarchical BiOBr hollow microspheres with dramatic CO2 photoreduction activity

J Zhao, Z Miao, Y Zhang, G Wen, L Liu, X Wang… - Journal of Colloid and …, 2021 - Elsevier
Conversion of carbon dioxide into useful chemicals has attracted great attention. However,
the significant bottlenecks facing in the field are the poor conversion efficiency of CO 2 and …

Single‐Atom Sn on Tensile‐Strained ZnO Nanosheets for Highly Efficient Conversion of CO2 into Formate

Y Zhang, H Jang, X Ge, W Zhang, Z Li… - Advanced Energy …, 2022 - Wiley Online Library
In general, commercial ZnO owns the poor selectivity and activity toward electroreduction
CO2 to formate. In contrast, the numbers of Sn‐based nanomaterials are reported as …

Defective Metal Oxides: Lessons from CO2RR and Applications in NOxRR

TS Bui, EC Lovell, R Daiyan, R Amal - Advanced Materials, 2023 - Wiley Online Library
Sluggish reaction kinetics and the undesired side reactions (hydrogen evolution reaction
and self‐reduction) are the main bottlenecks of electrochemical conversion reactions, such …

The integration of bio-catalysis and electrocatalysis to produce fuels and chemicals from carbon dioxide

X Tan, J Nielsen - Chemical Society Reviews, 2022 - pubs.rsc.org
The dependence on fossil fuels has caused excessive emissions of greenhouse gases
(GHGs), leading to climate changes and global warming. Even though the expansion of …