Radical ligand-containing single-molecule magnets

S Demir, IR Jeon, JR Long, TD Harris - Coordination Chemistry Reviews, 2015 - Elsevier
Single-molecule magnets represent the ultimate size limit for spin-based information storage
and processing; however, such applications require large spin relaxation barriers and …

Playing with organic radicals as building blocks for functional molecular materials

I Ratera, J Veciana - Chemical Society Reviews, 2012 - pubs.rsc.org
The literature has shown numerous contributions on the synthesis and physicochemical
properties of persistent organic radicals but there are a lesser number of reports about their …

Electronic and Spintronic Open-Shell Macromolecules, Quo Vadis?

Y Tan, SN Hsu, H Tahir, L Dou, BM Savoie… - Journal of the …, 2022 - ACS Publications
Open-shell macromolecules (ie, polymers containing radical sites either along their
backbones or at the pendant sites of repeat units) have attracted significant attention owing …

Electro-optical π-radicals: design advances, applications and future perspectives

P Murto, H Bronstein - Journal of Materials Chemistry C, 2022 - pubs.rsc.org
The unique open-shell electronic structure of neutral π-radicals has inspired research on
novel molecular materials for over a century. In recent years, rapid development in carbon …

The fruitful introduction of chirality and control of absolute configurations in molecular magnets

C Train, M Gruselle, M Verdaguer - Chemical Society Reviews, 2011 - pubs.rsc.org
In this critical review, it is shown how the introduction of chirality and the control of the
absolute configurations of chiral elements in molecular magnets allow obtaining …

Redox-active ligands for chemical, electrochemical, and photochemical molecular conversions

A Nakada, T Matsumoto, HC Chang - Coordination Chemistry Reviews, 2022 - Elsevier
A central issue in the design of reactions and catalysts based on metal complexes is the
hybridization of functional ligands with metal atoms. Recent studies have demonstrated that …

Formazanate coordination compounds: synthesis, reactivity, and applications

JB Gilroy, E Otten - Chemical Society Reviews, 2020 - pubs.rsc.org
Formazans (Ar1-NH-NCR3-NN-Ar5), a class of nitrogen-rich and highly colored compounds,
have been known since the late 1800s and studied more closely since the early 1940s …

Recent advances in the chemistry of benzo [e][1, 2, 4] triazinyl radicals

FJM Rogers, PL Norcott, ML Coote - Organic & Biomolecular …, 2020 - pubs.rsc.org
Benzo [e][1, 2, 4] triazinyl, or Blatter radicals, are stable free radicals, first reported by Blatter
in 1968. In contrast to their nitroxide counterparts, their properties can be modified more …

Magnetic Bistability in an Organic Radical-Based Charge Transfer Cocrystal

W Lai, Y Bu, W Xiao, H Liu, J Guo, L Zhao… - Journal of the …, 2023 - ACS Publications
We report herein an organic charge transfer cocrystal complex, consisting of a stable radical
TPVr and an electron acceptor TCNQF 4, as a rare sort of all-organic-based magnetic …

A radically configurable six-state compound

JC Barnes, AC Fahrenbach, D Cao, SM Dyar… - Science, 2013 - science.org
Most organic radicals possess short lifetimes and quickly undergo dimerization or oxidation.
Here, we report on the synthesis by radical templation of a class of air-and water-stable …