Hypervalent iodine (III) compounds have found wide application in modern organic
chemistry as environmentally friendly reagents and catalysts. Hypervalent iodine reagents …

Presently, the major cornerstone of the research community is to develop green as well as
sustainable protocols involving inexpensive catalysts and/or reagents without the usage of …

Porous architectures characterized by parallel channels arranged in honeycomb or
rectangular patterns are identified in two polymorphic crystals of a zwitterionic 4 …

Three diaryliodonium tetrachloroaurates (III),[Ar1IAr2][AuCl4](Ar1/Ar2= Ph/Ph (1), Ph/Mes
(2), o-(C6H4) 2 (3)), were obtained as solids (62–80%) by the metathetical reaction of …

X-ray crystallography data revealed the dichotomy of thiocyanate-involving noncovalent
interactions in [Ar1Ar2I](SCN), as reflected in the generation of two types of supramolecular …

A single-crystal X-ray diffraction (XRD) study of diaryliodonium tetrachloroaurates (or, in the
recent terminology, tetrachloridoaurates),[(p-XC6H4) 2I][AuCl4](X= Cl, 1; Br, 2), was …

The structure-directing “key-to-lock” interaction of double σ-(IIII)-hole donating iodonium
cations with the O-flanked pseudo-lacune rims of [β-Mo8O26] 4− gives halogen-bonded …

Benzyne has long captivated the attention of chemists and has gained numerous synthetic
achievements. Among typical benzyne generation methods, removal of two vicinal …

Here, we report the method for copper‐catalyzed N‐arylation of diverse oxadiazolones by
diaryliodonium salts under mild conditions in high yields (up to 92%) using available CuI as …

Since the 1950s, diaryliodonium (III) salts have been demonstrated to participate in various
arylation reactions, forming aryl–heteroatom and aryl–carbon bonds. Incorporating the …