C–C bond cleavages of cyclopropenes: operating for selective ring-opening reactions
R Vicente - Chemical Reviews, 2020 - ACS Publications
This review highlights key reactivities relying on C–C bond cleavages of cyclopropenes.
Metal-catalyzed and metal-free transformations are covered in reactions involving direct ring …
Metal-catalyzed and metal-free transformations are covered in reactions involving direct ring …
Creating stereocenters within acyclic systems by C–C bond cleavage of cyclopropanes
Recent developments in the stereoselective synthesis of polysubstituted cyclopropanes
nowadays allow chemists to easily access these strained rings with high diastereo-and …
nowadays allow chemists to easily access these strained rings with high diastereo-and …
Asymmetric Preparation of Polysubstituted Cyclopropanes Based on Direct Functionalization of Achiral Three-Membered Carbocycles: Focus Review
In addition to the appealing synthetic transformations that cyclopropanes present, they are
also part of larger molecular structures that possess a wide range of biological properties …
also part of larger molecular structures that possess a wide range of biological properties …
Regio-and diastereoselective carbometalation reaction of cyclopropenes
Conspectus The various facets of the chemistry of cyclopropane derivatives, the smallest
carbocycle, are amazingly diverse and continue to fascinate theoreticians, synthetic or …
carbocycle, are amazingly diverse and continue to fascinate theoreticians, synthetic or …
Recent developments in cyclopropene chemistry
P Li, X Zhang, M Shi - Chemical Communications, 2020 - pubs.rsc.org
The transformations of cyclopropenes have attracted the attention of organic chemists for
decades. As readily accessible strained carbocycles, cyclopropenes show a diverse range …
decades. As readily accessible strained carbocycles, cyclopropenes show a diverse range …
The Indenyl Effect: Accelerated C−H Amidation of Arenes via Ind*RhIII Nitrene Transfer Catalysis**
L Atkin, DL Priebbenow - Angewandte Chemie, 2023 - Wiley Online Library
Investigations into C− H amidation reactions catalysed by cationic half‐sandwich d6 metal
complexes revealed that the indenyl‐derived catalyst [Ind* RhCl2] 2 significantly accelerated …
complexes revealed that the indenyl‐derived catalyst [Ind* RhCl2] 2 significantly accelerated …
Enantioselective construction of acyclic quaternary carbon stereocenters: palladium-catalyzed decarboxylative allylic alkylation of fully substituted amide enolates
P Starkov, JT Moore, DC Duquette… - Journal of the …, 2017 - ACS Publications
We report a divergent and modular protocol for the preparation of acyclic molecular
frameworks containing newly created quaternary carbon stereocenters. Central to this …
frameworks containing newly created quaternary carbon stereocenters. Central to this …
Asymmetric copper‐catalyzed carbomagnesiation of cyclopropenes
The highly diastereo‐and enantioselective formation of polysubstituted cyclopropanes was
easily achieved through the asymmetric copper‐catalyzed carbomagnesiation reaction of …
easily achieved through the asymmetric copper‐catalyzed carbomagnesiation reaction of …
Efficient and stereodivergent synthesis of unsaturated acyclic fragments bearing contiguous stereogenic elements
J Bruffaerts, D Pierrot, I Marek - Nature chemistry, 2018 - nature.com
Synthetic organic strategies that enable the catalytic and rapid assembly of a large array of
organic compounds that possess multiple stereocentres in acyclic systems are somewhat …
organic compounds that possess multiple stereocentres in acyclic systems are somewhat …
Nucleophilic substitution at quaternary carbon stereocenters
Cyclopropyl carbinol derivatives undergo a regio-and stereoselective nucleophilic
substitution at the quaternary carbon center, with pure inversion of configuration, to provide …
substitution at the quaternary carbon center, with pure inversion of configuration, to provide …