[HTML][HTML] Coordination chemistry of elemental phosphorus

L Giusti, VR Landaeta, M Vanni, JA Kelly, R Wolf… - Coordination Chemistry …, 2021 - Elsevier
This review comprehensively covers the coordination chemistry of elemental phosphorus
during the years 2011–2020. The main part is dedicated to the activation of white …

Organometallic polyphosphorus complexes as diversified building blocks in coordination chemistry

E Peresypkina, A Virovets, M Scheer - Coordination Chemistry Reviews, 2021 - Elsevier
The complexes containing cyclo-P n ligands which are π-coordinated to a metal atom have
been known since the late 1970 s. Cyclo-P n ligands being cyclic aromatic P-donors …

Stabilization of Tetrahedral P4 and As4 Molecules as Guests in Polymeric and Spherical Environments

C Schwarzmaier, A Schindler, C Heindl… - Angewandte Chemie …, 2013 - Wiley Online Library
Chemistry as a science has originated from the exploration and handling of native elements
such as sulfur or noble metals that allowed the formulation of the crucial concept of a …

Diantimony Complexes [CpR2Mo2(CO)4(μ,η2‐Sb2)] (CpR=C5H5, C5H4tBu) as Unexpected Ligands Stabilizing Silver(I)n (n=1–4) Monomers …

PA Shelyganov, M Elsayed Moussa… - Angewandte Chemie …, 2023 - Wiley Online Library
Synthesis and reactivity of transition metal compounds bearing “naked” pnictogen atoms is
an active research area with remarkable bonding patterns observed in the formed …

Giant Rugby Ball [{CpBnFe(η5-P5)}24Cu96Br96] Derived from Pentaphosphaferrocene and CuBr2

C Heindl, EV Peresypkina, AV Virovets… - Journal of the …, 2015 - ACS Publications
The self-assembly of [CpBnFe (η5-P5)](CpBn= η5-C5 (CH2Ph) 5) with CuBr2 leads to the
formation of an unprecedented rugby ball-shaped supramolecule consisting of 24 units of …

Ferrocene and pentaphosphaferrocene: a comparative study regarding redox chemistry.

MV Butovskiy, G Balázs… - Angewandte …, 2013 - search.ebscohost.com
Pentaphosphaferrocene redox chemistry: Unprecedented dianionic and P P coupled and
monomeric products are obtained by the reduction of pentaphosphaferrocene with KH or K …

Sterically induced reductive linkage of iron polypnictides with bulky lanthanide complexes by ring-opening of THF

C Schoo, S Bestgen, M Schmidt… - Chemical …, 2016 - pubs.rsc.org
Reduction of [Cp* Fe (η5-E5)](E= P, As) with divalent lanthanide reagents usually leads to
reduction of [Cp* Fe (η5-E5)] followed by a Ln–E bond formation. In contrast, by using the …

Functionalization of a cyclo‐P5 Ligand by Main‐Group Element Nucleophiles

E Mädl, MV Butovskii, G Balázs… - Angewandte Chemie …, 2014 - Wiley Online Library
Unprecedented functionalized products with an η4‐P5 ring are obtained by the reaction of
[Cp* Fe (η5‐P5)](1; Cp*= η5‐C5Me5) with different nucleophiles. With LiCH2SiMe3 and …

Molecular Polyarsenides of the Rare‐Earth Elements

N Arleth, MT Gamer, R Köppe… - Angewandte Chemie …, 2016 - Wiley Online Library
Abstract Reduction of [Cp* Fe (η5‐As5)] with [Cp′′ 2Sm (thf)](Cp′′= η5‐1, 3‐(tBu)
2C5H3) under various conditions led to [(Cp′′ 2Sm)(μ, η4: η4‐As4)(Cp* Fe)] and [(Cp …

Complexes of Monocationic Group 13 Elements with Pentaphospha‐and Pentaarsaferrocene

M Fleischmann, S Welsch, H Krauss… - … A European Journal, 2014 - Wiley Online Library
Reactions of the sandwich complexes [Cp* Fe (η5‐E5)](Cp*= η5‐C5Me5; E= P (1), As (2))
with the monovalent Group 13 metals Tl+, In+, and Ga+ containing the weakly coordinating …