n-Type organic semiconducting polymers: stability limitations, design considerations and applications

S Griggs, A Marks, H Bristow… - Journal of Materials …, 2021 - pubs.rsc.org
This review outlines the design strategies which aim to develop high performing n-type
materials in the fields of organic thin film transistors (OTFT), organic electrochemical …

Direct (hetero) arylation polymerization: simplicity for conjugated polymer synthesis

JR Pouliot, F Grenier, JT Blaskovits, S Beaupré… - Chemical …, 2016 - ACS Publications
Direct (hetero) arylation polymerization (DHAP) has recently been established as an
environmentally benign method for the preparation of conjugated polymers. This synthetic …

Transformation of step-growth polymerization into living chain-growth polymerization

T Yokozawa, Y Ohta - Chemical reviews, 2016 - ACS Publications
Conventional condensation polymerization proceeds in a stepgrowth polymerization
manner, and it was thought that “living” condensation polymerization was essentially …

Defect-free naphthalene diimide bithiophene copolymers with controlled molar mass and high performance via direct arylation polycondensation

R Matsidik, H Komber, A Luzio, M Caironi… - Journal of the …, 2015 - ACS Publications
A highly efficient, simple, and environmentally friendly protocol for the synthesis of an
alternating naphthalene diimide bithiophene copolymer (PNDIT2) via direct arylation …

Low‐energy‐consumption and electret‐free photosynaptic transistor utilizing poly (3‐hexylthiophene)‐based conjugated block copolymers

WC Yang, YC Lin, S Inagaki, H Shimizu… - Advanced …, 2022 - Wiley Online Library
Neuromorphic computation possesses the advantages of self‐learning, highly parallel
computation, and low energy consumption, and is of great promise to overcome the …

Tuning mechanical and optoelectrical properties of poly (3-hexylthiophene) through systematic regioregularity control

JS Kim, JH Kim, W Lee, H Yu, HJ Kim, I Song… - …, 2015 - ACS Publications
While the regioregularity (RR) of conjugated polymers is known to have a strong influence
on their inherent properties, systematic study of the RR effect has been limited due to the …

Tin-free direct C–H arylation polymerization for high photovoltaic efficiency conjugated copolymers

AS Dudnik, TJ Aldrich, ND Eastham… - Journal of the …, 2016 - ACS Publications
A new and highly regioselective direct C–H arylation polymerization (DARP) methodology
enables the reproducible and sustainable synthesis of high-performance π-conjugated …

25th anniversary article: high‐mobility hole and electron transport conjugated polymers: how structure defines function

Y Olivier, D Niedzialek, V Lemaur, W Pisula… - Advanced …, 2014 - Wiley Online Library
The structural organization of three different families of semicrystalline π‐conjugated
polymers is reported (poly (3‐hexylthiophene)(P3HT), poly [2, 6‐(4, 4‐bis‐alkyl‐4H …

Direct arylation polymerization: A guide to optimal conditions for effective conjugated polymers

NS Gobalasingham, BC Thompson - Progress in Polymer Science, 2018 - Elsevier
The rapid increase in the breadth and scope of transformations that involve metal-promoted
activation of Csingle bondH bonds is fundamentally changing the field of synthetic …

Optimization of direct arylation polymerization (DArP) through the identification and control of defects in polymer structure

AE Rudenko, BC Thompson - Journal of Polymer Science Part …, 2015 - Wiley Online Library
As a newly emerged protocol for the synthesis of conjugated polymers, direct arylation
polymerization (DArP) is an environmentally friendly and cost‐effective alternative to …