A supermolecular building approach for the design and construction of metal–organic frameworks

V Guillerm, D Kim, JF Eubank, R Luebke… - Chemical Society …, 2014 - pubs.rsc.org
In this review, we describe two recently implemented conceptual approaches facilitating the
design and deliberate construction of metal–organic frameworks (MOFs), namely …

The importance of highly connected building units in reticular chemistry: thoughtful design of metal–organic frameworks

V Guillerm, M Eddaoudi - Accounts of Chemical Research, 2021 - ACS Publications
Conspectus The prediction of crystal structures assembled in three dimensions has been
considered for a long time, simultaneously as a chemical wasteland and a certain growth …

MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)

C Janiak, JK Vieth - New Journal of Chemistry, 2010 - pubs.rsc.org
This review (over 380 references) summarizes metal–organic frameworks (MOFs), Materials
Institute Lavoisier (MILs), iso-reticular metal–organic frameworks (IR-MOFs), porous …

Effects of functionalization, catenation, and variation of the metal oxide and organic linking units on the low-pressure hydrogen adsorption properties of metal− organic …

JLC Rowsell, OM Yaghi - Journal of the American Chemical …, 2006 - ACS Publications
The dihydrogen adsorption isotherms of eight metal− organic frameworks (MOFs), measured
at 77 K up to a pressure of 1 atm, have been examined for correlations with their structural …

Control of vertex geometry, structure dimensionality, functionality, and pore metrics in the reticular synthesis of crystalline metal− organic frameworks and Polyhedra

H Furukawa, J Kim, NW Ockwig… - Journal of the …, 2008 - ACS Publications
Metal− organic polyhedra and frameworks (MOPs and MOFs) were prepared by linking
square units M2 (CO2) 4 (M= Cu and Zn) with a variety of organic linkers designed to control …

Hydrolytic stability in hemilabile metal–organic frameworks

LN McHugh, MJ McPherson, LJ McCormick… - Nature Chemistry, 2018 - nature.com
Highly porous metal–organic frameworks (MOFs), which have undergone exciting
developments over the past few decades, show promise for a wide range of applications …

From molecules to materials: Molecular paddle-wheel synthons of macromolecules, cage compounds and metal–organic frameworks

M Köberl, M Cokoja, WA Herrmann, FE Kuehn - Dalton Transactions, 2011 - pubs.rsc.org
Metal–organic frameworks (MOF) are becoming a more and more important class of
functional materials. Yet, very often, the synthesis of MOFs is not easy to control and requires …

Highly Selective Sorption and Luminescent Sensing of Small Molecules Demonstrated in a Multifunctional Lanthanide Microporous Metal–Organic Framework …

H Li, W Shi, K Zhao, Z Niu, H Li… - Chemistry–A European …, 2013 - Wiley Online Library
A rare, robust microporous lanthanide metal–organic framework with 1D honeycomb‐type
channels is presented. Excellent adsorption capabilities for N2, H2, and CO2 and significant …

Template-directed synthesis of nets based upon octahemioctahedral cages that encapsulate catalytically active metalloporphyrins

Z Zhang, L Zhang, L Wojtas, M Eddaoudi… - Journal of the …, 2012 - ACS Publications
meso-Tetra (N-methyl-4-pyridyl) porphine tetratosylate (TMPyP) templates the synthesis of
six new metal–organic materials by the reaction of benzene-1, 3, 5-tricarboxylate with …

Macrocycle-based metal-organic frameworks

H Zhang, R Zou, Y Zhao - Coordination Chemistry Reviews, 2015 - Elsevier
Organic struts incorporating macrocycles have been employed recently to construct
extended metal-organic frameworks (MOFs), which opened up the possibility of forming …