Chemoselective hydrogenation of carbonyl compounds over heterogeneous catalysts

P Mäki-Arvela, J Hájek, T Salmi, DY Murzin - Applied Catalysis A: General, 2005 - Elsevier
Chemoselective hydrogenation of unsaturated aldehydes and ketones over heterogeneous
catalysts is a demanding task. The achieved selectivity levels depend both on the electronic …

Recent advances in selective hydrogenation of cinnamaldehyde over supported metal-based catalysts

X Wang, X Liang, P Geng, Q Li - Acs Catalysis, 2020 - ACS Publications
Selective hydrogenation of cinnamaldehyde (CAL) is an important reaction because the
main products, cinnamic alcohol (COL) and hydrocinnamaldehyde (HCAL), are used in …

Analysis of kinetics and reaction pathways in the aqueous-phase hydrogenation of levulinic acid to form γ-valerolactone over Ru/C

OA Abdelrahman, A Heyden, JQ Bond - ACS catalysis, 2014 - ACS Publications
Reaction pathways and kinetics governing the Ru-catalyzed hydrogenation of levulinic acid
(LA) in the aqueous phase to form γ-valerolactone (GVL) were considered in a packed bed …

Easy α-alkylation of ketones with alcohols through a hydrogen autotransfer process catalyzed by RuCl2 (DMSO) 4

R Martínez, DJ Ramón, M Yus - Tetrahedron, 2006 - Elsevier
The electrophilic α-alkylation of ketones with alcohols is accomplished by a hydrogen
autotransfer process catalyzed by RuCl2 (DMSO) 4. The reaction can produce either simple …

Rational nanoparticle synthesis to determine the effects of size, support, and K dopant on Ru activity for levulinic acid hydrogenation to γ-valerolactone

S Cao, JR Monnier, CT Williams, W Diao… - Journal of …, 2015 - Elsevier
With worldwide petroleum resources dwindling and greenhouse gas emissions rising, it is
urgent to find renewable replacements for petroleum-derived products. A biomass-derived …

Selectivity control in Pt-catalyzed cinnamaldehyde hydrogenation

LJ Durndell, CMA Parlett, NS Hondow, MA Isaacs… - Scientific reports, 2015 - nature.com
Chemoselectivity is a cornerstone of catalysis, permitting the targeted modification of specific
functional groups within complex starting materials. Here we elucidate key structural and …

Selective hydrogenation of cinnamaldehyde with PtFex/Al2O3@ SBA-15 catalyst: Enhancement in activity and selectivity to unsaturated alcohol by Pt-FeOx and Pt …

H Pan, J Li, J Lu, G Wang, W Xie, P Wu, X Li - Journal of catalysis, 2017 - Elsevier
Selective hydrogenation of cinnamaldehyde (CAL) to cinnamyl alcohol (COL) was
conducted over a series of FeO x-doped Pt catalysts supported on a 15 wt% Al 2 O 3@ SBA …

Regulating the states of Ni species by controlling the silanols of MCM-41 support to promote the hydrogenation of maleic anhydride

J Zhuang, S Yan, P Zhang, X Liu, Y Zhao, Y Yu… - Fuel, 2023 - Elsevier
Nickel (Ni) supported on MCM-41 zeolite as hydrogenation catalysts have been widely
applied in various reactions, however, the synergism between Ni and the support remains …

Kinetic modeling of levulinic acid hydrogenation to γ-valerolactone in water using a carbon supported Ru catalyst

AS Piskun, HH Van de Bovenkamp… - Applied Catalysis A …, 2016 - Elsevier
Abstract γ-Valerolactone (GVL) is considered a very interesting green, bio-based platform
chemical with high application potential for the production of both biofuels and biobased …

RuCl2 (DMSO) 4 catalyzes the β-alkylation of secondary alcohols with primary alcohols through a hydrogen autotransfer process

R Martínez, DJ Ramón, M Yus - Tetrahedron, 2006 - Elsevier
The electrophilic β-alkylation of secondary alcohols with primary alcohols is accomplished
by a hydrogen autotransfer process catalyzed by RuCl2 (DMSO) 4. The reaction can …