Aerobic copper-catalyzed organic reactions
SE Allen, RR Walvoord, R Padilla-Salinas… - Chemical …, 2013 - ACS Publications
The chemistry of copper is extremely rich because it can easily access Cu0, CuI, CuII, and
CuIII oxidation states allowing it to act through one-electron or two-electron processes. As a …
CuIII oxidation states allowing it to act through one-electron or two-electron processes. As a …
Catechol oxidase and phenoxazinone synthase: Biomimetic functional models and mechanistic studies
SK Dey, A Mukherjee - Coordination Chemistry Reviews, 2016 - Elsevier
The impetus to modeling of enzyme active sites comes from their potential to provide insight
to the mechanistic pathways of the native enzymes, establish the role of that particular metal …
to the mechanistic pathways of the native enzymes, establish the role of that particular metal …
Insertion of a hydroxido bridge into a diphenoxido dinuclear copper (II) complex: Drastic change of the magnetic property from strong antiferromagnetic to …
A Biswas, LK Das, MGB Drew, C Diaz… - Inorganic …, 2012 - ACS Publications
A diphenoxido-bridged dinuclear copper (II) complex,[Cu2L2 (ClO4) 2](1), has been
synthesized using a tridentate reduced Schiff base ligand, 2-[[2-(diethylamino) ethylamino] …
synthesized using a tridentate reduced Schiff base ligand, 2-[[2-(diethylamino) ethylamino] …
Single and multiple site Cu (II) catalysts for benzyl alcohol and catechol oxidation reactions
Cu (II) catalysts both in homogeneous and heterogeneous form were synthesized to bring
the distinction between the single and multiple site catalysis. The single site mononuclear …
the distinction between the single and multiple site catalysis. The single site mononuclear …
A trinuclear zinc–schiff base complex: biocatalytic activity and cytotoxicity
A novel trinuclear zinc (II) complex [Zn3L2 (μ‐O2CCH3) 2 (CH3OH) 4](1) that contains an N,
O‐donor Schiff base ligand {H2L= 2‐[(2‐hydroxyphenylimino) methyl]‐6‐methoxyphenol} …
O‐donor Schiff base ligand {H2L= 2‐[(2‐hydroxyphenylimino) methyl]‐6‐methoxyphenol} …
A combined experimental and theoretical investigation on the role of halide ligands on the catecholase-like activity of mononuclear nickel (ii) complexes with a phenol …
J Adhikary, P Chakraborty, S Das… - Inorganic …, 2013 - ACS Publications
Three new mononuclear nickel (II) complexes, namely,[NiL1 (H2O) 3] I2· H2O (1),[NiL1
(H2O) 3] Br2· H2O (2), and [NiL1 (H2O) 3] Cl2· 2H2O (3)[HL1= 2-[(2-piperazin-1 …
(H2O) 3] Br2· H2O (2), and [NiL1 (H2O) 3] Cl2· 2H2O (3)[HL1= 2-[(2-piperazin-1 …
Structure and antioxidant superoxide dismutase activity of copper (II) hydrazone complexes
YP Singh, RN Patel, Y Singh, RJ Butcher… - Polyhedron, 2017 - Elsevier
Three new mixed ligand hydrazone complexes viz.,[Cu (L)(neocuprin)] NO 3· H 2 O 1,[Cu
(L)(HL)] ClO 4 2 and [Cu 2 (2-(2-pyridyl) benzimidazole) 2 (L) 2] ClO 4 3 (L= N′-[(E)-phenyl …
(L)(HL)] ClO 4 2 and [Cu 2 (2-(2-pyridyl) benzimidazole) 2 (L) 2] ClO 4 3 (L= N′-[(E)-phenyl …
The synthesis, characterization and catecholase activity of dinuclear cobalt (II/III) complexes of an O-donor rich Schiff base ligand
SK Dey, A Mukherjee - New Journal of Chemistry, 2014 - pubs.rsc.org
Three dinuclear CoIII/II complexes [(CoIII2 (H2L) 2 (OAc) 2)]· CH3OH (1),[CoIICoIII (H2L) 2
(OAc)]· 2CH3OH· H2O (2), and [CoIICoIII (H2L) 2 (CH3CN)(H2O)] Cl· CH3CN· 4H2O (3)[H4L …
(OAc)]· 2CH3OH· H2O (2), and [CoIICoIII (H2L) 2 (CH3CN)(H2O)] Cl· CH3CN· 4H2O (3)[H4L …
Tailored design, synthesis, and catalytic aspects of mononuclear cis-dichloro copper (ii) complexes with simple DPA-derived tridentate ligands and their biomimicking …
The activation of molecular oxygen remains a persistent challenge to the scientific
community owing to its poor selectivity, especially towards organic substrates. In biological …
community owing to its poor selectivity, especially towards organic substrates. In biological …
A review on bio-functional models of catechol oxidase probed by less explored first row transition metals
Catecholase activity is a biological process in which type-3 active site of a copper enzyme,
named catechol oxidase, catalyzes oxidation of o-diphenolic substrates to the …
named catechol oxidase, catalyzes oxidation of o-diphenolic substrates to the …