Homogeneous and heterogeneous catalysts for hydrogenation of CO 2 to methanol under mild conditions

ST Bai, G De Smet, Y Liao, R Sun, C Zhou… - Chemical Society …, 2021 - pubs.rsc.org
In the context of a carbon neutral economy, catalytic CO2 hydrogenation to methanol is one
crucial technology for CO2 mitigation providing solutions for manufacturing future fuels …

Homogeneous catalysis for sustainable hydrogen storage in formic acid and alcohols

K Sordakis, C Tang, LK Vogt, H Junge… - Chemical …, 2018 - ACS Publications
Hydrogen gas is a storable form of chemical energy that could complement intermittent
renewable energy conversion. One of the main disadvantages of hydrogen gas arises from …

CO2 Hydrogenation to Formate and Methanol as an Alternative to Photo- and Electrochemical CO2 Reduction

WH Wang, Y Himeda, JT Muckerman… - Chemical …, 2015 - ACS Publications
Carbon dioxide is one of the end products of combustion, and is not a benign component of
the atmosphere. The concentration of CO2 in the atmosphere has reached unprecedented …

Metal–ligand cooperation

JR Khusnutdinova, D Milstein - … Chemie International Edition, 2015 - Wiley Online Library
Metal–ligand cooperation (MLC) has become an important concept in catalysis by transition
metal complexes both in synthetic and biological systems. MLC implies that both the metal …

Formic acid as a hydrogen storage material–development of homogeneous catalysts for selective hydrogen release

D Mellmann, P Sponholz, H Junge… - Chemical Society Reviews, 2016 - pubs.rsc.org
Formic acid (FA, HCO2H) receives considerable attention as a hydrogen storage material. In
this respect, hydrogenation of CO2 to FA and dehydrogenation of FA are crucial reaction …

Pincer‐type complexes for catalytic (De) hydrogenation and transfer (De) hydrogenation reactions: recent progress

S Werkmeister, J Neumann, K Junge… - … –A European Journal, 2015 - Wiley Online Library
Pincer complexes are becoming increasingly important for organometallic chemistry and
organic synthesis. Since numerous applications for such catalysts have been developed in …

Recent Advances in Catalysis with Transition‐Metal Pincer Compounds

H Valdés, MA García‐Eleno… - …, 2018 - Wiley Online Library
Pincer complexes are useful tools for organic synthesis. Their high stability and easy
functionalization have allowed the development of novel catalytic systems that have had a …

Chemoselective hydrogenation of aldehydes under mild, base-free conditions: manganese outperforms rhenium

M Glatz, B Stöger, D Himmelbauer, LF Veiros… - ACS …, 2018 - ACS Publications
Several hydride Mn (I) and Re (I) PNP pincer complexes were applied as catalysts for the
homogeneous chemoselective hydrogenation of aldehydes. Among these,[Mn (PNP-i …

An update on formic acid dehydrogenation by homogeneous catalysis

C Guan, Y Pan, T Zhang, MJ Ajitha… - Chemistry–An Asian …, 2020 - Wiley Online Library
Formic acid (FA) has been extensively studied as one of the most promising hydrogen
energy carriers today. The catalytic decarboxylation of FA ideally leads to the formation of …

Bifunctionality of Re Supported on TiO2 in Driving Methanol Formation in Low-Temperature CO2 Hydrogenation

N Phongprueksathat, KW Ting, S Mine, Y Jing… - ACS …, 2023 - ACS Publications
Low temperature and high pressure are thermodynamically more favorable conditions to
achieve high conversion and high methanol selectivity in CO2 hydrogenation. However, low …