Density functional theory for transition metals and transition metal chemistry

CJ Cramer, DG Truhlar - Physical Chemistry Chemical Physics, 2009 - pubs.rsc.org
We introduce density functional theory and review recent progress in its application to
transition metal chemistry. Topics covered include local, meta, hybrid, hybrid meta, and …

A fluorescent turn-on probe for cyanide anion detection based on an AIE active cobalt (II) complex

MT Gabr, FC Pigge - Dalton Transactions, 2018 - pubs.rsc.org
A new tetradentate polypyridine ligand that displays aggregation induced emission (AIE)
characteristics has been synthesized. A coordination complex with CoCl2 has been …

Electrochemiluminescent functionalizable cyclometalated thiophene-based iridium (III) complexes

M Bandini, M Bianchi, G Valenti, F Piccinelli… - Inorganic …, 2010 - ACS Publications
A family of new functional bis-cyclometalated thiophene-based cationic iridium complexes
have been prepared and fully characterized. The introduction of formyl groups into the …

Redox-active ferrocene grafted on H-terminated Si (111): Electrochemical characterization of the charge transport mechanism and dynamics

C Fontanesi, ED Como, D Vanossi, M Montecchi… - Scientific reports, 2019 - nature.com
Electroactive self-assembled monolayers (SAMs) bearing a ferrocene (Fc) redox couple
were chemically assembled on H-terminated semiconducting degenerate-doped n-type Si …

Polypyridyl ruthenium (II) complexes with tetrazolate-based chelating ligands. Synthesis, reactivity, and electrochemical and photophysical properties

S Stagni, E Orselli, A Palazzi, L De Cola… - Inorganic …, 2007 - ACS Publications
In this contribution, we report the synthesis, the chemical and photophysical
characterization, and the study of the reactivity toward electrophiles of two mononuclear …

Neutral and dianionic Ru (II) bathophenanthrolinedisulfonate complexes: a route to enhance electrochemiluminescence performance in aqueous media

L Della Ciana, S Zanarini, R Perciaccante… - The Journal of …, 2010 - ACS Publications
We report the strong enhancement of ECL intensity and duration in neutral and dianionic Ru
(II) complexes bearing mixed 2, 2′-bipyridine (bpy) and bathophenanthrolinedisulfonate …

Mononuclear nickel (II) complexes coordinated by polypyridyl ligands

H Hadadzadeh, G Mansouri, A Rezvani, HR Khavasi… - Polyhedron, 2011 - Elsevier
Three mononuclear polypyridyl complexes of Ni (II),[Ni (Ph2phen) 3](PF6) 2· CH3CN (1),[Ni
(dpa) 2 (phen)](PF6) 2 (2) and [Ni (bpy) 3](PF6) 2 (3), where Ph2phen is 4, 7-diphenyl-1, 10 …

Distinguishing between Dexter and rapid sequential electron transfer in covalently linked donor− acceptor assemblies

M Soler, JK McCusker - Journal of the American Chemical Society, 2008 - ACS Publications
The syntheses, physical, and photophysical properties of a family of complexes having the
general formula [M2 (L)(mcb)(Ru (4, 4 '-(X) 2-bpy) 2)](PF6) 3 (where M= MnII or ZnII, X= CH3 …

TMP-cadmiate: A base for Efficient and Chemoselective Deprotonative Metallation Reactions of Aromatic Compounds

F Mongin, M Uchiyama - Current Organic Chemistry, 2011 - ingentaconnect.com
Efficient deprotonative cadmiation reactions of functionalized aromatics including
heterocycles have been realized using TMP-cadmiate,(TMP) 3CdLi (TMP= 2, 2, 6, 6 …

Electrodeposition of Cu on PEDOT for a hybrid solid-state electronic device

M Vizza, G Pappaianni, W Giurlani, A Stefani… - Surfaces, 2021 - mdpi.com
Conductive polymers are nowadays attracting great attention for their peculiar mechanical,
electrical and optical proprieties. In particular, PEDOT can be used in a wide range of …