Hydroamination, the addition of an N–H bond across a C–C multiple bond, is a reaction with
a great synthetic potential. Important advances have been made in the last decades …

The past decade has witnessed some remarkable advances in our appreciation of the
structural and reaction chemistry of the heavier alkaline earth (Ae= Mg, Ca, Sr, Ba) elements …

Organometallic chemistry is generally considered the key to homogeneous catalysis, which,
although a century old, is still today a very dynamic discipline. 1 The past decade has seen …

Disclosed herein is a general catalytic system for the intermolecular anti‐Markovnikov
hydroamination of alkenes. By using an organocatalytic photoredox system, α‐and β …

Enantioselective synthesis of β-chiral amines has been achieved via copper-catalyzed
hydroamination of 1, 1-disubstituted alkenes with hydroxylamine esters in the presence of a …

The easily electronically and sterically tunable β-diketiminates are widely used auxiliary
ligands for the creation of a wide range of metal complexes with various oxidation states in …

Early Main Group Metal Catalysis gives a comprehensive overview of catalytic reactions in
the presence of group 1 and group 2 metals. Chapters are ordered to reaction type, contain …

Despite the routine employment of Grignard reagents and Hauser bases as stoichiometric
carbanion reagents in organic and inorganic synthesis, a defined reaction chemistry …

The heavier group 2 complexes [M {N (SiMe3) 2} 2] 2 (1, M= Ca; 2, M= Sr) and [M {CH
(SiMe3) 2} 2 (THF) 2](3, M= Ca; 4, M= Sr) are shown to be effective precatalysts for the …

Over the past decade s-block metal catalysis has undergone a transformation from being an
esoteric curiosity to a well-established and consolidated field towards sustainable synthesis …