The addition of a B–H bond to an unsaturated bond (polarized or unpolarized) is a powerful
and atom-economic tool for the synthesis of organoboranes. In recent years, s-block …

This review highlights recent advances in the research of organoaluminum complexes in
catalysis. Many fundamental transformations can be carried out by aluminum catalysts, such …

Organoboranes obtained from hydroboration reactions are one of the important classes of
compounds that could be used to provide valuable synthons for follow-up transformations …

The design of new reductive routes to low oxidation state aluminium (Al) compounds offers
the opportunity to better understand redox processes at the metal centre and develop …

Lithium-promoted hydroboration of alkynes and alkenes using commercially available
hexamethyldisilazane lithium as a precatalyst and HBpin as a hydride source has been …

In this work, the molecular aluminium dihydride complex bearing an N, N'‐chelated
conjugated bis‐guanidinate (CBG) ligand is used as a catalyst for reducing a wide range of …

The hydroboration of alkynes with bis (pinacolato) diboron (B2pin2) using H2O or untreated
H2O as a solvent is a challenging task. This work reports the aqueous N-heterocyclic …

Aluminum hydride cations,[L AlH]+[HB (C6F5) 3]−(1) and [L AlH]+[B (C6F5) 4]−(2), and the
methyl aluminum cation,[L AlMe]+[B (C6F5) 4]−(3)(L=[{(2, 6-i Pr2C6H3N) P (Ph2)} 2N]), due …

The synthesis, characterization, and catalytic application of six aluminum alkyl complexes
supported by various imino-phosphanamidinate chalcogenide ligands are described. Six …

The protoboration of alkenes and alkynes with B2pin2 (pin= OCMe2CMe2O) using a
heterogeneous CeO2 nanorods catalyst has been developed to afford the corresponding …