Strong metal–support interaction in heterogeneous catalysts

Z Luo, G Zhao, H Pan, W Sun - Advanced Energy Materials, 2022 - Wiley Online Library
Strong metal–support interaction (SMSI) in supported metal catalysts, typically accompanied
by the formation of encapsulation layers over metal nanoparticles, has drawn intense …

The reformation of catalyst: From a trial-and-error synthesis to rational design

L Wang, J Wu, S Wang, H Liu, Y Wang, D Wang - Nano Research, 2024 - Springer
The appropriate catalysts can accelerate the reaction rate and effectively boost the efficient
conversion of various molecules, which is of great importance in the study of chemistry …

Engineering heterogeneous catalysis with strong metal–support interactions: characterization, theory and manipulation

T Pu, W Zhang, M Zhu - Angewandte Chemie International …, 2023 - Wiley Online Library
Strong metal–support interactions (SMSI) represent a classic yet fast‐growing area in
catalysis research. The SMSI phenomenon results in the encapsulation and stabilization of …

Induced activation of the commercial Cu/ZnO/Al2O3 catalyst for the steam reforming of methanol

D Li, F Xu, X Tang, S Dai, T Pu, X Liu, P Tian, F Xuan… - Nature Catalysis, 2022 - nature.com
The surface structure of heterogeneous catalysts is closely associated with their catalytic
performance. Current efforts for structural modification mainly focus on improving the catalyst …

Enhanced CO2 utilization in dry reforming of methane achieved through nickel-mediated hydrogen spillover in zeolite crystals

Q Zhu, H Zhou, L Wang, L Wang, C Wang, H Wang… - Nature Catalysis, 2022 - nature.com
Transformation of CO2 into precursors for chemicals and fuels by self-contained reducing
gas contaminants (for example, CH4) is attractive from a carbon economy perspective …

Overturning CO2 Hydrogenation Selectivity with High Activity via Reaction-Induced Strong Metal–Support Interactions

H Xin, L Lin, R Li, D Li, T Song, R Mu… - Journal of the …, 2022 - ACS Publications
Encapsulation of metal nanoparticles by support-derived materials known as the classical
strong metal–support interaction (SMSI) often happens upon thermal treatment of supported …

Manipulating local coordination of copper single atom catalyst enables efficient CO2-to-CH4 conversion

Y Dai, H Li, C Wang, W Xue, M Zhang, D Zhao… - Nature …, 2023 - nature.com
Electrochemical CO2 conversion to methane, powered by intermittent renewable electricity,
provides an entrancing opportunity to both store renewable electric energy and utilize …

Highly efficient and stable methane dry reforming enabled by a single-site cationic Ni catalyst

Q Cheng, X Yao, L Ou, Z Hu, L Zheng, G Li… - Journal of the …, 2023 - ACS Publications
Zeolite-supported nickel (Ni) catalysts have been extensively studied for the dry reforming of
methane (DRM). It is generally believed that prior to or during the reaction, Ni is reduced to a …

Photo-thermo semi-hydrogenation of acetylene on Pd1/TiO2 single-atom catalyst

Y Guo, Y Huang, B Zeng, B Han, M Akri, M Shi… - Nature …, 2022 - nature.com
Semi-hydrogenation of acetylene in excess ethylene is a key industrial process for ethylene
purification. Supported Pd catalysts have attracted most attention due to their superior …

Order-of-magnitude increase in rate of methane dry reforming over Ni/CeO2-SiC catalysts by microwave catalysis

Y Shi, L Wang, M Wu, F Wang - Applied Catalysis B: Environmental, 2023 - Elsevier
Methane dry reforming (MDR) produces syngas from CH 4 and CO 2. The endothermic
character of the reaction forces the lower surface catalyst temperature than targeted furnace …