Recognition in the domain of molecular chirality: from noncovalent interactions to separation of enantiomers

P Peluso, B Chankvetadze - Chemical Reviews, 2022 - ACS Publications
It is not a coincidence that both chirality and noncovalent interactions are ubiquitous in
nature and synthetic molecular systems. Noncovalent interactivity between chiral molecules …

Supramolecular polymerization through kinetic pathway control and living chain growth

M Wehner, F Würthner - Nature Reviews Chemistry, 2020 - nature.com
Supramolecular polymers exhibit fascinating structures, and their properties, and thus
applications, depend both on the strength and dynamics of the non-covalent bonds and on …

Supramolecular helical systems: helical assemblies of small molecules, foldamers, and polymers with chiral amplification and their functions

E Yashima, N Ousaka, D Taura, K Shimomura… - Chemical …, 2016 - ACS Publications
In this review, we describe the recent advances in supramolecular helical assemblies
formed from chiral and achiral small molecules, oligomers (foldamers), and helical and …

Supramolecular polymerization: a conceptual expansion for innovative materials

PK Hashim, J Bergueiro, EW Meijer, T Aida - Progress in Polymer Science, 2020 - Elsevier
The research field of supramolecular polymerization has dramatically progressed in the last
three decades, and much deeper insights into its new mechanisms, including kinetic and …

A rational strategy for the realization of chain-growth supramolecular polymerization

J Kang, D Miyajima, T Mori, Y Inoue, Y Itoh, T Aida - Science, 2015 - science.org
Over the past decade, major progress in supramolecular polymerization has had a
substantial effect on the design of functional soft materials. However, despite recent …

Competition between chiral solvents and chiral monomers in the helical bias of supramolecular polymers

ML Ślęczkowski, MFJ Mabesoone, P Ślęczkowski… - Nature Chemistry, 2021 - nature.com
Solute–solvent interactions are key for the assembly and proper functioning of
biomacromolecules and play important roles in many fields of organic and polymer …

Single-crystalline ultrathin 2D porous nanosheets of chiral metal–organic frameworks

Y Liu, L Liu, X Chen, Y Liu, Y Han… - Journal of the American …, 2021 - ACS Publications
Two-dimensional (2D) materials with highly ordered in-plane nanopores are crucial for
numerous applications, but their rational synthesis and local structural characterization …

Impact of alkyl spacer length on aggregation pathways in kinetically controlled supramolecular polymerization

S Ogi, V Stepanenko, J Thein… - Journal of the American …, 2016 - ACS Publications
We have investigated the kinetic and thermodynamic supramolecular polymerizations of a
series of amide-functionalized perylene bisimide (PBI) organogelator molecules bearing …

Living supramolecular polymerization

RD Mukhopadhyay, A Ajayaghosh - Science, 2015 - science.org
Most polymers that we encounter, like those used in grocery bags and soda bottles, are
formed from small molecules (monomers) held together by strong covalent bonds. In …

Living supramolecular polymerization of fluorinated cyclohexanes

O Shyshov, SV Haridas, L Pesce, H Qi, A Gardin… - Nature …, 2021 - nature.com
The development of powerful methods for living covalent polymerization has been a key
driver of progress in organic materials science. While there have been remarkable reports …