Conspectus Transition-metal catalyzed cross-coupling reactions are fundamental reactions
in organic chemistry, facilitating strategic bond formations for accessing natural products …

Disproportionation and comproportionation reactions have become increasingly important
electron transfer events in organometallic chemistry and catalysis. The renewed interest in …

Mechanistic investigations of the Ni-catalyzed asymmetric reductive alkenylation of N-
hydroxyphthalimide (NHP) esters and benzylic chlorides are reported. Investigations of the …

Polypyridine-ligated nickel complexes are widely used as privileged catalysts in a variety of
cross-coupling reactions. The rapid adoption of these complexes is tentatively attributed to …

While the oxidative addition of Ni (I) to aryl iodides has been commonly proposed in catalytic
methods, an in-depth mechanistic understanding of this fundamental process is still lacking …

Electrochemical asymmetric catalysis has emerged as a sustainable and promising
approach to the production of chiral compounds and the utilization of both the anode and …

The merger of electrochemistry and transition metal catalysis has emerged as a powerful
tool to join two electrophiles in an enantioselective manner. However, the development of …

The capture of carbon-centered radicals at a nickel (II) center is commonly featured in recent
cross-coupling and metallaphotoredox catalytic reactions. Despite its widespread …

Nickel-catalyzed cross-coupling reactions often employ bidentate π-acceptor N-ligands to
facilitate radical pathways. This report presents the synthesis and characterization of a …

Conspectus Nickel excels at facilitating selective radical chemistry, playing a pivotal role in
metalloenzyme catalysis and modern cross-coupling reactions. Radicals, being nonpolar …