Aromatics and cyclic molecules in molecular clouds: A new dimension of interstellar organic chemistry

MC McCarthy, BA McGuire - The Journal of Physical Chemistry A, 2021 - ACS Publications
Astrochemistry lies at the nexus of astronomy, chemistry, and molecular physics. On the
basis of precise laboratory data, a rich collection of more than 200 familiar and exotic …

Detection of two interstellar polycyclic aromatic hydrocarbons via spectral matched filtering

BA McGuire, RA Loomis, AM Burkhardt, KLK Lee… - Science, 2021 - science.org
Unidentified infrared emission bands are ubiquitous in many astronomical sources. These
bands are widely, if not unanimously, attributed to collective emissions from polycyclic …

Discovery of the pure polycyclic aromatic hydrocarbon indene (c-C9H8) with GOTHAM observations of TMC-1

AM Burkhardt, KLK Lee, PB Changala… - The Astrophysical …, 2021 - iopscience.iop.org
Polycyclic aromatic hydrocarbons (PAHs) have long been invoked in the study of interstellar
and protostellar sources, but the unambiguous identification of any individual PAH has …

2021 census of interstellar, circumstellar, extragalactic, protoplanetary disk, and exoplanetary molecules

BA McGuire - The Astrophysical Journal Supplement Series, 2022 - iopscience.iop.org
To date, 241 individual molecular species, composed of 19 different elements, have been
detected in the interstellar and circumstellar medium by astronomical observations. These …

Interstellar detection of the highly polar five-membered ring cyanocyclopentadiene

MC McCarthy, KLK Lee, RA Loomis, AM Burkhardt… - Nature …, 2021 - nature.com
Much like six-membered rings, five-membered rings are ubiquitous in organic chemistry,
frequently serving as the building blocks for larger molecules, including many of biochemical …

Discovery of interstellar 2-cyanoindene (2-C9H7CN) in GOTHAM observations of TMC-1

ML Sita, PB Changala, C Xue… - The Astrophysical …, 2022 - iopscience.iop.org
We present laboratory rotational spectroscopy of five isomers of cyanoindene (2-, 4-, 5-, 6-,
and 7-cyanoindene) using a cavity Fourier transform microwave spectrometer operating …

Interstellar detection of 2-cyanocyclopentadiene, C5H5CN, a second five-membered ring toward TMC-1

KLK Lee, PB Changala, RA Loomis… - The Astrophysical …, 2021 - iopscience.iop.org
Using radio observations with the Green Bank Telescope, evidence has now been found for
a second five-membered ring in the dense cloud Taurus Molecular Cloud-1 (TMC-1). Based …

Overview of desorption parameters of volatile and complex organic molecules-A systematic dig through the experimental literature

NFW Ligterink, M Minissale - Astronomy & Astrophysics, 2023 - aanda.org
Context. Many molecules observed in the interstellar medium are thought to result from the
thermal desorption of ices. Parameters such as the desorption energy and pre-exponential …

An investigation of spectral line stacking techniques and application to the detection of HC11N

RA Loomis, AM Burkhardt, CN Shingledecker… - Nature …, 2021 - nature.com
As the inventory of interstellar molecules continues to grow, the gulf between small species,
whose individual rotational lines can be observed with radio telescopes, and large ones …

A Search for Heterocycles in GOTHAM Observations of TMC-1

TJ Barnum, MA Siebert, KLK Lee… - The Journal of …, 2022 - ACS Publications
We have conducted an extensive search for nitrogen-, oxygen-, and sulfur-bearing
heterocycles toward Taurus Molecular Cloud 1 (TMC-1) using the deep, broadband …