Direct C–H bond arylation of (hetero) arenes is a very convenient approach for the synthesis
of a wide variety of molecular targets, including compounds of pharmaceutical interest and π …

The electron is an efficient catalyst for conducting various types of radical cascade reaction
that proceed by way of radical and radical ion intermediates. But because electrons are …

Biological photosynthesis uses the energy of several visible light photons for the challenging
oxidation of water, whereas chemical photocatalysis typically involves only single-photon …

Many recent studies have used KO t Bu in organic reactions that involve single electron
transfer; in the literature, the electron transfer is proposed to occur either directly from the …

Photosynthetic organisms exploit antenna chromophores to absorb light and transfer
excitation energy to the reaction center where redox reactions occur. In contrast, in visible …

We report herein a simple, metal-and additive-free, photoinduced borylation of haloarenes,
including electron-rich fluoroarenes, as well as arylammonium salts directly to boronic acids …

The consecutive photo-induced electron-transfer (conPET) process found with perylene
diimide (PDI) overcomes the limitation of visible-light photocatalysis and sheds light on …

Despite the wide use of aryl radicals in organic synthesis, current methods to prepare them
from aryl halides, carboxylic acids, boronic acids, and diazonium salts suffer from limitations …

Efficient and practical visible-light photoredox borylation of aryl halides and subsequent
aerobic oxidative hydroxylation were developed. The protocols use readily available aryl …

Newly discovered tris (diisocyanide) molybdenum (0) complexes are Earth-abundant
isoelectronic analogues of the well-known class of [Ru (α-diimine) 3] 2+ compounds with …