Direct photocatalyzed hydrogen atom transfer (d-HAT) can be considered a method of
choice for the elaboration of aliphatic C–H bonds. In this manifold, a photocatalyst (PCHAT) …

The construction of carbon–carbon bonds is a central tenet of modern synthetic chemistry.
Metal-catalyzed C–H functionalization can serve as a particularly powerful tool for achieving …

Methyl groups are well understood to play a critical role in pharmaceutical molecules,
especially those bearing saturated heterocyclic cores. Accordingly, methods that install …

The synergistic control of the SH2 transition states of hydrogen abstraction by polar and
steric effects provides a promising strategy in achieving site-selective C (sp3)–H …

Here we report the direct conversion of strong, aliphatic C (sp 3)–H bonds into the
corresponding alkyl sulfinic acids via decatungstate photocatalysis. This transformation has …

The decatungstate anion [W10O32] 4–is a widely used photocatalyst for promoting
hydrogen atom transfer (HAT) reactions. The mechanism implicated in the activation of …

The decatungstate anion,[W10O32] 4–or DT, is a useful photocatalyst for organic
transformations involving C–H functionalization. Herein, we leverage the unique photoredox …

Three decatungstates with short carbon chains as the cations, such as tetrabutylammonium
decatungstate ([(C4H9) 4N] 4W10O32), tetramethylammonium decatungstate ([(CH3) 4N] …

One of the main goals of organic chemists is to find easy, environmentally friendly, and cost
effective methods for the synthesis of industrially important compounds. Photocatalysts have …

The direct benzylation of electrophilic alkenes with alkylbenzenes has been achieved by
decatungstate photocatalysis in a high ionic strength medium (5: 1 acetonitrile/water mixed …